940002-36-8

Basic information

• Product Name: propyl(5,10,15,20-tetramesitylporphyrinato)rhodium(III)
• Synonyms: propyl(5,10,15,20-tetramesitylporphyrinato)rhodium(III)
• CAS NO: 940002-36-8
• Molecular Weight: 927.05
• Mol File: 940002-36-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: propyl(5,10,15,20-tetramesitylporphyrinato)rhodium(III)(CAS DataBase Reference)
• NIST Chemistry Reference: propyl(5,10,15,20-tetramesitylporphyrinato)rhodium(III)(940002-36-8)
• EPA Substance Registry System: propyl(5,10,15,20-tetramesitylporphyrinato)rhodium(III)(940002-36-8)

Safety Data

• Hazardous Substances Data: 940002-36-8(Hazardous Substances Data)

Upstream product

• 121393-39-3 5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate rhodium(II) 
• 96724-61-7 1,1,3,3-tetrapropylisoindolin-2-oxyl 
• 603-35-0 triphenylphosphine 
• 1234321-53-9 1,1,3,3-tetrabutylisoindolin-2-oxyl 
• 142-96-1 dibutyl ether 
• 85990-32-5 (5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) iodide 
• 124535-65-5 (5,10,15,20-tetramesitylporphyrinato)rhodium(III) hydride 
• 161407-97-2 (5,10,15,20-tetramesitylporphyrinato)rhodium(III) chloride 
• 5558-78-1 2-phenyl-pentanenitrile 

Relevant articles and documents

Room-temperature selective aliphatic carbon-carbon bond activation and functionalization of ethers by rhodium(II) porphyrin

Selective aliphatic carbon(α)-carbon(β) bond activation of ethers by (5,10,15,20-tetramesitylporphyrinato)rhodium(II) (Rh(tmp) (1)) was achieved at room temperature to yield corresponding rhodium porphyrin alkyls and the functionalized esters. Rh(tmp)OH was the proposed intermediate responsible for cleaving the C(α)-C(β) bond. The reaction is general for both straight- and branch-chain ethers.

Base-promoted, selective aliphatic carbon-carbon bond cleavage of ethers by rhodium(III) porphyrin complexes

Summary: Base-promoted, selective aliphatic carbon(α)carbon(β) bond activation (CCA) of ethers by (5,10,15,20tetramesitylporphyrinato) rhodium(III) iodide was achieved.