940003-64-5

Basic information

• Product Name: (Z)-1-(p-toluenesulfonyloxy)-9-dodecene
• Synonyms: (Z)-1-(p-toluenesulfonyloxy)-9-dodecene
• CAS NO: 940003-64-5
• Molecular Weight: 338.511
• Mol File: 940003-64-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Z)-1-(p-toluenesulfonyloxy)-9-dodecene(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-1-(p-toluenesulfonyloxy)-9-dodecene(940003-64-5)
• EPA Substance Registry System: (Z)-1-(p-toluenesulfonyloxy)-9-dodecene(940003-64-5)

Safety Data

• Hazardous Substances Data: 940003-64-5(Hazardous Substances Data)

Upstream product

• 71084-08-7 dodec-9-yn-1-ol 
• 35148-18-6 (Z)-9-dodecenol 
• 98-59-9 p-toluenesulfonyl chloride 

Relevant articles and documents

Asymmetric synthesis of long chain α-methyl-β-thiotrifluoromethyl ketones employing the SAMP-/RAMP-hydrazone alkylation methodology

The enantioselective synthesis of both enantiomers of (Z)-1,1,1-trifluoro-3-methyl-4-thia-13-octadecen-2-one and (Z)-1,1,1-trifluoro-3-methyl-4-thia-13-hexadecen-2-one (ee ≥90%), potential inhibitors of the pheromone action of two major maize pests Sesamia nonagrioides and Ostrinia nubilalis, is described. The key step is based upon a stereoselective alkylation with methyl iodide using the SAMP-/RAMP-chiral auxiliary methodology, followed by deprotection under non-racemization conditions.