94157-86-5

Basic information

• Product Name: phenyl cyclohexanepropionate
• Synonyms: phenyl cyclohexanepropionate;Cyclohexanepropionic acid phenyl ester
• CAS NO: 94157-86-5
• Molecular Formula: C₁₅H₂₀O₂
• Molecular Weight: 232.3181
• EINECS: 303-054-6
• Mol File: 94157-86-5.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 379.4°C at 760 mmHg
• Flash Point: 276.3°C
• Appearance: /
• Density: 1.027±0.06 g/cm3(Predicted)
• Vapor Pressure: 1.97E-06mmHg at 25°C
• CAS DataBase Reference: phenyl cyclohexanepropionate(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl cyclohexanepropionate(94157-86-5)
• EPA Substance Registry System: phenyl cyclohexanepropionate(94157-86-5)

Safety Data

• Hazardous Substances Data: 94157-86-5(Hazardous Substances Data)

Usage

InChI:InChI=1/C15H20O2/c1-12(14(16)17)15(10-6-3-7-11-15)13-8-4-2-5-9-13/h2,4-5,8-9,12H,3,6-7,10-11H2,1H3,(H,16,17)/p-1

Upstream product

• 39098-75-4 3-cyclohexylpropionyl chloride 
• 108-95-2 phenol 
• 110-82-7 cyclohexane 
• 1735-17-7 Cyclohexane-d12 
• 937-41-7 phenyl acrylate 
• 701-97-3 cyclohexanepropionic acid 
• 501-52-0 3-Phenylpropionic acid 
• 695-12-5 vinylcyclohexane 
• 1864-94-4 phenyl formate 
• 108-91-8 cyclohexylamine 
• 98-89-5 Cyclohexanecarboxylic acid 
• 126812-30-4 1,3-dioxoisoindolin-2-yl cyclohexanecarboxylate 
• 626-62-0 Cyclohexyl iodide 
• 201230-82-2 carbon monoxide 

Downstream Products

• 82350-71-8 3-cyclohexyl-1-(4-hydroxy-phenyl)-propan-1-one 
• 108975-02-6 3-cyclohexyl-1-(2-hydroxyphenyl)propan-1-one 

Relevant articles and documents

Convenient C(sp3)-H bond functionalisation of light alkanes and other compounds by iron photocatalysis

Light alkanes are natural organic carbon sources and widely distributed in nature. Transforming them into value-added fine chemicals affords attractively economic and ecological benefits as well as enormous chemical challenges. Herein, we report a practical iron-catalysed photoredox system for C(sp3)-H transformation of ethane, propane, and other light alkanes to C-N and C-C bonds under ambient temperature. The present method with abundant and inexpensive iron salts as photocatalysts exhibits high catalytic efficiency (turnover number up to 8000), mild conditions, and the convenience of being purified and scaled up without chromatography. A photo-induced ligand-to-metal charge transfer between Fe(iii) and Cl- generates a highly active chlorine radical that sequentially acts as hydrogen atom transfer catalyst. Therefore, the sustainable, convenient, and environmentally friendly system will find wide applications in high-value-added transformation of natural alkanes with novel inspiration not only for organic synthesis, but also for designing catalytically active organic/inorganic materials. This journal is

Visible-light-initiated manganese-catalyzed Giese addition of unactivated alkyl iodides to electron-poor olefins

Herein, we report a mild protocol for direct visible-light-initiated Giese addition of unactivated alkyl iodides to electron-poor olefins (Michael acceptors) with catalysis by decacarbonyl dimanganese, Mn2(CO)10, an inexpensive earth-abundant-metal catalyst. This protocol is compatible with a wide array of sensitive functional groups and has a broad substrate scope with regard to both the alkyl iodide and the Michael acceptor.

Catalyst-free alkyl carboxylate decarboxylation and decarboxylation Giese radical addition reaction

A catalyst-free alkyl carboxylate decarboxylation and decarboxylation Giese radical addition reaction is as follows: in a solution environment, an alkyl N-(acyloxy) phthalimide compound, hantzsch ester and an alkenyl compound react in an inert protective atmosphere under blue violet light irradiation with a wavelength range of 370-470 nm, and the equivalent ratio of alkyl N-(acyloxy) phthalimide compound to hantzsch ester to alkenyl compound is 1: 1-3: 1-2. The photoactivated hantzsch ester is converted into free radicals. Under the attack of the free radicals, the alkyl N-(acyloxy) phthalimide compound can undergo decarboxylation reaction without a catalyst and Giese radical addition reaction with the alkenyl compound.