94265-89-1

Basic information

• Product Name: bis(1-methyl-1-phenylethyl)disulfide
• Synonyms: bis(1-methyl-1-phenylethyl)disulfide
• CAS NO: 94265-89-1
• Molecular Weight: 302.505
• Mol File: 94265-89-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: bis(1-methyl-1-phenylethyl)disulfide(CAS DataBase Reference)
• NIST Chemistry Reference: bis(1-methyl-1-phenylethyl)disulfide(94265-89-1)
• EPA Substance Registry System: bis(1-methyl-1-phenylethyl)disulfide(94265-89-1)

Safety Data

• Hazardous Substances Data: 94265-89-1(Hazardous Substances Data)

Upstream product

• 16325-88-5 α,α-dimethylbenzylmercaptan 
• 41294-64-8 cumyl ethyl sulfide 
• 98-82-8 Isopropylbenzene 
• 97-39-2 1,3-Di(2-tolyl)guanidine 
• 13125-70-7 (+-)-methyl-(1-phenyl-ethyl)-sulfide 
• 109-72-8 n-butyllithium 

Downstream Products

• 1428366-12-4 C₁₅H₂₇NOSSi 
• 1428365-94-9 (R_s)-2-phenylpropyl-2-sulfinamide 
• 1428366-35-1 C₁₉H₂₃NOS 
• 1428366-36-2 C₂₃H₂₅NOS 
• 1428366-38-4 C₂₀H₂₅NOS 
• 1428366-40-8 C₂₀H₂₅NOS 
• 1428366-41-9 C₁₉H₂₂FNOS 
• 1428366-43-1 C₁₇H₂₁NO₂S 
• 1428366-45-3 C₁₇H₂₇NOS 
• 1428366-46-4 C₁₉H₂₉NOS 
• 1428366-48-6 C₂₁H₂₅NOS 
• 1428366-50-0 C₂₀H₂₅NOS 

Relevant articles and documents

CHIRAL 2-ARYLPROPYL-2-SULFINAMIDE AND CHIRAL N-2-ARYLPROPYL-2-SULFINYLIMINES AND SYNTHESIS THEREOF

Provided herein are novel chiral sulfinamide and imine compounds. Also provided herein are methods of synthesizing novel chiral sulfinamide and imine compounds comprising simplified purification methods when compared to prior methods. The novel chiral sulfinamide and imine compounds are useful, for example, in the synthesis of complex natural products and pharmaceutical important compounds.

Photosensitized electron transfer oxidation of sulfides: A steady-state study

The photosensitized electron-transfer oxidation of a series of ethyl sulfides RSEt (1, R = C12H25; 2, PhCH2CH 2; 3, PhCH2; 4, PhCMe2; 5, Ph2CH) has been examined in acetonitrile and the product distribution discussed on the basis of the mechanisms proposed. In nitrogen-flushed solutions, cleaved alcohols and alkenes are formed, whereas under oxygen, in reactions that are 10-70 times faster, sulfoxides and cleaved aldehydes and ketones are formed in addition to the afore-mentioned products. Two sensitizers are compared, 9,10-dicyanoanthracene (DCA) and 2,4,6-triphenylpyrylium tetrafluoroborate (TPP+BF4-), the former giving a higher proportion of the sulfoxide, the latter of cleaved carbonyls. The sulfoxidation is due to the contribution of the singlet oxygen path with DCA. Oxidative cleavage, on the other hand, occurs both with DCA and with TPP+ which is known to produce neither singlet oxygen nor the superoxide anion. This process involves deprotonation from the α position of the sulfide radical cation, but the TPP+ results suggest that O2.- is not necessarily involved and non-activated oxygen forms a weak adduct with the radical cation promoting α-hydrogen transfer, particularly with benzylic derivatives. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.

METALATION REACTIONS. VII. METALATION OF BENZYLALKYL AND β-PHENETHYLALKYL SULFIDES

The products from the reaction between n-butyllithium and benzylalkyl and β-phenethylalkyl sulfides followed by carbonation, have been investigated by GLC/MS analysis.With benzylalkyl sulfides metalation occurs at the benzylic position, and the corresponding carboxylic acid can be isolated, but side products from Wittig like rearrangement, cleavage of the thioether bond, and aliphatic and aromatic substitution are also obtained.No benzylic metalation or Wittig-like rearrangement products are obtained from β-phenethyl sulfides: instead cleavage of the thioether bond and aliphatic and aromatic substitution occur.