94286-34-7Relevant articles and documents
Enantioselective Catalyst Systems from Copper(II) Triflate and BINOL–Silanediol
Guan, Yong,Attard, Jonathan W.,Visco, Michael D.,Fisher, Thomas J.,Mattson, Anita E.
supporting information, p. 7123 - 7127 (2018/05/08)
Silanediol and copper catalysis are merged, for the first time, to create an enhanced Lewis acid catalyst system for enantioselective heterocycle functionalization. The promise of this silanediol and copper catalyst combination is demonstrated in the enantioselective addition of indoles to alkylidene malonates to give rise to the desirable adducts in excellent yield and high enantiomeric excess. From these studies, 1,1′-bi-2-naphthol (BINOL)-based silanediols emerge as one-of-a-kind cocatalysts. Their potential role in the reaction pathway is also discussed.
Unsaturated esters
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Page 6, (2010/01/31)
The present invention relates to new α,β-unsaturated esters of formula I. The new compounds exhibit an intense, very long lasting fruity-pineapple odor with green galbanum-type undertones.
Conformationally constrained amino acid compounds having affinity for the alpha2delta subunit of a calcium channel
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, (2008/06/13)
Novel substituted amino acids of formula are disclosed and are useful as agents in the treatment of epilepsy, faintness attacks, hypokinesia, cranial disorders, neurodegenerative disorders, depression, anxiety, panic, pain, and neuropathological disorders
