943-72-6

Basic information

• Product Name: (p-chlorobenzylidene)(tert-butyl)amine
• CAS NO: 943-72-6
• Molecular Weight: 195.692
• Mol File: 943-72-6.mol
• Article Data: 19

Chemical Properties

• CAS DataBase Reference: (p-chlorobenzylidene)(tert-butyl)amine(CAS DataBase Reference)
• NIST Chemistry Reference: (p-chlorobenzylidene)(tert-butyl)amine(943-72-6)
• EPA Substance Registry System: (p-chlorobenzylidene)(tert-butyl)amine(943-72-6)

Safety Data

• Hazardous Substances Data: 943-72-6(Hazardous Substances Data)

Upstream product

• 637-87-6 1-Chloro-4-iodobenzene 
• 119072-55-8 tert-butylisonitrile 
• 104-83-6 1-Chloro-4-(chloromethyl)benzene 
• 104-86-9 4-chlorobenzylamine 
• 75-64-9 tert-butylamine 
• 104-88-1 4-chlorobenzaldehyde 
• 46234-01-9 N-(4′-chlorobenzyl)-2-methylpropan-2-amine 

Downstream Products

• 1246633-36-2 4-chloro-2-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)benzaldehyde 
• 1112209-14-9 C₁₃H₁₆BClO₃ 
• 104-88-1 4-chlorobenzaldehyde 
• 40117-30-4 N-<(4-Chlorophenyl)methylene>-2-methyl-2-propanamine N-Oxide 
• 82044-40-4 (2R,3R)-2-tert-Butyl-3-(4-chloro-phenyl)-oxaziridine 
• 23898-60-4 2-tert-butyl-3-(p-chlorophenyl)oxaziridine 
• 46234-01-9 N-(4′-chlorobenzyl)-2-methylpropan-2-amine 
• 42498-40-8 N-tert-butyl-4-chlorobenzamide 
• 153164-03-5 (E)-7-p-chlorobenzylidene-2H,6H-naphtho<1,8-b,c>furan-2,6-dione 

Relevant articles and documents

Diastereodivergent [3 + 2] Annulation of Aromatic Aldimines with Alkenes via C-H Activation by Half-Sandwich Rare-Earth Catalysts

Stereodivergent catalysis is of great importance, as it can allow efficient access to all possible stereoisomers of a given product with multiple stereocenters from the same set of starting materials. We report herein the first diastereodivergent [3 + 2]

2D sp2 Carbon-Conjugated Porphyrin Covalent Organic Framework for Cooperative Photocatalysis with TEMPO

2D covalent organic frameworks (COFs) are receiving ongoing attention in semiconductor photocatalysis. Herein, we present a photocatalytic selective chemical transformation by combining sp2 carbon-conjugated porphyrin-based covalent organic framework (Por-sp2c-COF) photocatalysis with TEMPO catalysis illuminated by 623 nm red light-emitting diodes (LEDs). Highly selective conversion of amines into imines was swiftly afforded in minutes. Specifically, the π-conjugation of porphyrin linker leads to extensive absorption of red light; the sp2 ?C=C? double bonds linkage ensures the stability of Por-sp2c-COF under high concentrations of amine. Most importantly, we found that crystalline framework of Por-sp2c-COF is pivotal for cooperative photocatalysis with (2,2,6,6-tetramethylpiperidin-1-yl)oxyl (TEMPO). This work foreshadows that the outstanding hallmarks of COFs, particularly crystallinity, could be exploited to address energy and environmental challenges by cooperative photocatalysis.

Carbonylation Access to Phthalimides Using Self-Sufficient Directing Group and Nucleophile

Herein we report a novel palladium-catalyzed oxidative carbonylation reaction for the synthesis of phthalimides with high atom- and step-economy. In our strategy, the imine and H2O, which are generated in situ from the condensation of aldehyde and amine, serve as self-sufficient directing group and nucleophile, respectively. This method provides rapid access to phthalimides starting from readily available materials in a one-pot manner. Various phthalimide derivatives are constructed efficiently, including medicinally and biologically active phthalimide-containing compounds.