94324-54-6

Basic information

• Product Name: Toluene-4-sulfonate4-amino-3-(3,6-dihydroxy-tricyclo[6.2.2.0^2,7]dodeca-2,4,6,9-tetraen-4-ylsulfanyl)-1,5-dimethyl-4H-[1,2,4]triazol-1-ium;
• CAS NO: 94324-54-6
• Molecular Weight: 502.615
• Mol File: 94324-54-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Toluene-4-sulfonate4-amino-3-(3,6-dihydroxy-tricyclo[6.2.2.0^2,7]dodeca-2,4,6,9-tetraen-4-ylsulfanyl)-1,5-dimethyl-4H-[1,2,4]triazol-1-ium;(CAS DataBase Reference)
• NIST Chemistry Reference: Toluene-4-sulfonate4-amino-3-(3,6-dihydroxy-tricyclo[6.2.2.0^2,7]dodeca-2,4,6,9-tetraen-4-ylsulfanyl)-1,5-dimethyl-4H-[1,2,4]triazol-1-ium;(94324-54-6)
• EPA Substance Registry System: Toluene-4-sulfonate4-amino-3-(3,6-dihydroxy-tricyclo[6.2.2.0^2,7]dodeca-2,4,6,9-tetraen-4-ylsulfanyl)-1,5-dimethyl-4H-[1,2,4]triazol-1-ium;(94324-54-6)

Safety Data

• Hazardous Substances Data: 94324-54-6(Hazardous Substances Data)

Upstream product

• 61230-66-8 1,5-dimethyl-4-amino-1,2,4-triazolium-3-thiolate 
• 104-15-4 toluene-4-sulfonic acid 
• 94324-60-4 5,6,7,8-tetrahydro-5,8-ethano-1,4-naphthoquinone 

Relevant articles and documents

1,4-Addition of Triazolium Thiolates to Quinones.

In the presence of aprotic acid, 1,2,4-triazolium-3-thiolates 1 undergo 1,4-Michael additions to quinones to fortm the corresponding thioether-substituted hydroquinones salts 2.When, however, tetrafluoroboric acid is added to a stirred aqueous suspension of triazolium thiolate 1a and p-benzoquinone, the 2,5-bis(triazolium thiolate) adduct 6, rather than the expected monoadduct 5, is isolated.Since o-quinones are extremely reactive and often difficult to isolate, they can be generated in situ by oxidation of the corresponding catechols with hydrogen peroxide in the presence of a protic acid and then trapped by a triazolium thiolate to form thioether hydroquinone salts 8.Triazolium thiolate 1a adds to a 1,4-naphtoquinone imine to give the (triazoliothio)-4-(benzenesulfonamido)-1-naphtolsalt 11.Triazoliotioquinone tetrafluoroborates 16, which can be isolated as crystalline yellow salts, are rapidly formed by oxidation of the corresponding hydroquinone salts 2 with nitrosonium tetrafluoroborate in acetonitrile.