94352-93-9

Basic information

• Product Name: Benzenamine, N-[3-(trimethylsilyl)-2-propynyl]-
• CAS NO: 94352-93-9
• Molecular Formula: C12H17NSi
• Molecular Weight: 203.359
• Mol File: 94352-93-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzenamine, N-[3-(trimethylsilyl)-2-propynyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N-[3-(trimethylsilyl)-2-propynyl]-(94352-93-9)
• EPA Substance Registry System: Benzenamine, N-[3-(trimethylsilyl)-2-propynyl]-(94352-93-9)

Safety Data

• Hazardous Substances Data: 94352-93-9(Hazardous Substances Data)

Upstream product

• 81634-46-0 5,5-dimethyl-1-phenyl-1-aza-5-sila-1-hexen-3-yne 
• 38002-45-8 3-bromo-1-(trimethylsilyl)-1-propyne 
• 62-53-3 aniline 
• 14465-74-8 N-phenyl-N-prop-2-ynylamine 
• 75-77-4 chloro-trimethyl-silane 

Downstream Products

• 122278-57-3 α-chloro-α-methylthio-N-(3-trimethylsilylprop-2-ynyl)acetanilide 
• 122278-58-4 3-methylthio-1-phenyl-4-trimethylsilylmethylenepyrrolidin-2-one 

Relevant articles and documents

Synthesis of substituted quinolines by the electrophilic cyclization of n-(2-alkynyl)anilines

A wide variety of substituted quinolines are readily synthesized under mild reaction conditions by the 6-endo-dig electrophilic cyclization of N-(2-alkynyl)anilines by ICl, I2, Br2, PhSeBr, and p-O2NC6H4SCl. The reaction affords 3-halogen-, selenium- and sulfur-containing quinolines in moderate to good yields in the presence of various functional groups. Analogous quinolines bearing a hydrogen in the 3-position have been synthesized by the Hg(OTf)2-catalyzed ring closure of these same alkynylanilines.

REDUCTION OF IMINES OF SILICON-CONTAINING ACETYLENIC ALDEHYDES BY METAL HYDRIDE COMPLEXES

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