944450-45-7

Basic information

• Product Name: Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-dm-segphos][(R,R)-dpen]
• Synonyms: Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-dm-segphos][(R,R)-dpen];RuCl2[(R)(DMSEGPHOS)][(R,(R))(DPEN)];RuCl2[(R)-dm-segphos(regR)][(R,R)-dpen];Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-dm-segphos(R)][(R,R)-dpen];(R,R)-DPEN;RuCl2[(R)-dm-segphos(regR)][(R,R)-dpen] RuCl2[(R)-dm-segphos][(R,R)-dpen]
• CAS NO: 944450-45-7
• Molecular Formula: C60H60Cl2N2O4P2Ru
• Molecular Weight: 1107.052922
• Mol File: 944450-45-7.mol
• Article Data: 0

Chemical Properties

• Appearance: yellow/Powder
• Storage Temp.: 2-8°C
• Sensitive: air sensitive
• CAS DataBase Reference: Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-dm-segphos][(R,R)-dpen](CAS DataBase Reference)
• NIST Chemistry Reference: Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-dm-segphos][(R,R)-dpen](944450-45-7)
• EPA Substance Registry System: Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-dm-segphos][(R,R)-dpen](944450-45-7)

Safety Data

• WGK Germany: 3
• Hazardous Substances Data: 944450-45-7(Hazardous Substances Data)

Usage

Description

Dichloro(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-dm-segphos][(R,R)-dpen] is a complex organometallic compound that serves as a catalyst in various chemical reactions. It is characterized by its unique structure, which includes a ruthenium(II) center coordinated to a bis(phosphine) ligand and a diamine ligand. Dichloro(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-dm-segphos][(R,R)-dpen] is known for its high catalytic activity and selectivity in enantioselective hydrogenation reactions.

Uses

Used in Pharmaceutical Industry:
Dichloro(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-dm-segphos][(R,R)-dpen] is used as a catalyst for the enantioselective preparation of chiral amino alcohols and their derivatives. These chiral compounds are crucial building blocks in the synthesis of various pharmaceuticals, agrochemicals, and natural products. The use of this catalyst allows for the production of enantiomerically pure compounds, which is essential for the development of effective and safe drugs.
Used in Chemical Synthesis:
In the field of chemical synthesis, Dichloro(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-dm-segphos][(R,R)-dpen] is employed as a catalyst for asymmetric hydrogenation reactions. This process enables the selective reduction of prochiral substrates, such as amino ketones, to produce chiral products with high enantioselectivity. The use of this catalyst facilitates the synthesis of enantiomerically pure compounds, which are valuable in various applications, including the production of specialty chemicals and the development of new materials.
Used in Research and Development:
Dichloro(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-dm-segphos][(R,R)-dpen] is also utilized in research and development settings. Scientists and chemists use this catalyst to study enantioselective hydrogenation reactions and to develop new synthetic methods for the preparation of chiral compounds. The insights gained from these studies can lead to the discovery of more efficient and environmentally friendly catalytic systems, as well as the development of novel chiral compounds with potential applications in various industries.