945000-87-3

Basic information

• Product Name: 4-bromo-3-(phenylthio)-1H-indole
• Synonyms: 4-bromo-3-(phenylthio)-1H-indole
• CAS NO: 945000-87-3
• Molecular Formula: C₁₄H₁₀BrNS
• Molecular Weight: 304
• Mol File: 945000-87-3.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4-bromo-3-(phenylthio)-1H-indole(CAS DataBase Reference)
• NIST Chemistry Reference: 4-bromo-3-(phenylthio)-1H-indole(945000-87-3)
• EPA Substance Registry System: 4-bromo-3-(phenylthio)-1H-indole(945000-87-3)

Safety Data

• Hazardous Substances Data: 945000-87-3(Hazardous Substances Data)

Upstream product

• 52488-36-5 4-bromo-1H-indole 
• 108-98-5 thiophenol 
• 80-17-1 benzenesufonyl hydrazide 
• 618-41-7 Benzenesulfinic acid 
• 591-50-4 iodobenzene 
• 17356-08-0 thiourea 

Downstream Products

• 945000-88-4 4-bromo-3-(phenylsulfonyl)-1H-indole 

Relevant articles and documents

Recyclable Cellulose-Derived Fe3O4@Pd NPs for Highly Selective C–S Formation by Heterogeneously C–H Sulfenylation of Indoles

Abstract: An efficient and convenient method was developed for the preparation of 3-sulfenylindoles via a cellulose-derived Fe3O4@Pd NPs catalyzed heterogeneously C–H sulfenylation of indoles. This approach provides an effective synthetic route to an important class of indoles derivatives and features high efficiency, easy operation, good practicality, and environmental friendliness. The recoverable catalyst was separated from the reaction mixture using an outside magnetic field and can be recycled five times without huge loss of catalytic performance. Graphic Abstract: An efficient method was developed for the preparation of 3-sulfenylindoles via cellulose-derived Fe3O4@Pd NPs catalyzed heterogeneously C–H sulfenylation of indoles.[Figure not available: see fulltext.].

Iodine-catalyzed regioselective sulfenylation of indoles with sulfonyl hydrazides

New S in town: Sulfonyl hydrazides smoothly undergo sulfenylation with indoles in the presence of 10 mol % I2 to give structurally diverse indole thioethers in moderate to excellent yields with extremely high regioselectivity. This study paves the way for the use of sulfonyl hydrazides as unique sulfur electrophiles in chemical synthesis. Copyright

SULFONYL SUBSTITUTED 1H-INDOLES AS LIGANDS FOR THE 5-HYDROXYTRYPTAMINE RECEPTORS

The present invention is directed to compounds of Formula I: which are modulators of the 5-hydroxtryptamine-6 and 5-hydroxytryptamine-2A receptors and which are inhibitors of norepinephrine reuptake. The compounds of the invention, and pharmaceutical comp