94514-67-7Relevant articles and documents
Nitrations of Acylamino- and Nitrodibenzo-p-dioxins
Oliver, James E.
, p. 1073 - 1080 (2007/10/02)
Nitrations of 1- and 2-acylamino (and nitro) dibenzo-p-dioxins were employed to achieve regioselective further functionalization of these compounds.The choice of nitrating conditions and/or acyl substituent (CH3CO vs.CF3CO) often dictated into which ring the first nitro group was directed.In almost all cases, nitrations at the 2,3,7,8-positions were highly favored over nitrations at the 1,4,6,9-positions; with ammonium nitrate/trifluoroacetic anhydride in tetrahydrofuran, however, nitration of 1-(trifluoroacetylamino)dibenzo-p-dioxin proceeded predomonantly at the 4-position.