946828-66-6

Basic information

• Product Name: ((C₂H₅O)2PSN(C₆H₅)2P)2(CH₂)6
• Synonyms: ((C₂H₅O)2PSN(C₆H₅)2P)2(CH₂)6
• CAS NO: 946828-66-6
• Molecular Weight: 788.869
• Mol File: 946828-66-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ((C₂H₅O)2PSN(C₆H₅)2P)2(CH₂)6(CAS DataBase Reference)
• NIST Chemistry Reference: ((C₂H₅O)2PSN(C₆H₅)2P)2(CH₂)6(946828-66-6)
• EPA Substance Registry System: ((C₂H₅O)2PSN(C₆H₅)2P)2(CH₂)6(946828-66-6)

Safety Data

• Hazardous Substances Data: 946828-66-6(Hazardous Substances Data)

Upstream product

• 1516-67-2 O,O-diethyl phosphorazidothioate 
• 19845-69-3 1,6-bis(diphenylphosphino)hexane 

Downstream Products

• 946829-14-7 Ag⁽¹⁺⁾*((C₂H₅O)2PSN(C₆H₅)2P)2(CH₂)6*SbF₆^(1-)=Ag((C₂H₅O)2PSN(C₆H₅)2P)2(CH₂)6(SbF₆) 

Relevant articles and documents

Silver(i) complexes of N-thiophosphorylated bis(iminophosphorane) ligands: From monomers to polymers

Treatment of diphosphines Ph2P(CH2) nPPh2 (n = 1, 2, 4, 6) and [Fe(η5-C 5H4PR′2)2] (R′ = Ph, iPr) with a two-fold excess of (RO)2P(S)N3 (R = Et, Ph) results in the high-yield formation of the N-thiophosphorylated bis(iminophosphorane) derivatives (CH2)n[P{NP(S)(OR) 2}Ph2]2 and Fe(η5-C 5H4[P{NP(S)(OR)2}R′2]) 2, respectively. The reactions of these ligands with AgSbF 6 in a 1: 1 molar ratio have been investigated. The resulting silver(i) complexes, derived from the selective coordination of the PS units, have been characterized by IR, NMR and MS (FAB) spectroscopy and, in selected cases, by X-ray crystallography. Monomeric, dimeric and polymeric solid-state structures, depending on the nature of the ligand backbone, have been found. The Royal Society of Chemistry 2007.