94686-18-7

Basic information

• Product Name: 1,2-Diphenyloctan
• Synonyms: 1,2-Diphenyloctan
• CAS NO: 94686-18-7
• Molecular Weight: 266.426
• Mol File: 94686-18-7.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1,2-Diphenyloctan(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-Diphenyloctan(94686-18-7)
• EPA Substance Registry System: 1,2-Diphenyloctan(94686-18-7)

Safety Data

• Hazardous Substances Data: 94686-18-7(Hazardous Substances Data)

Upstream product

• 110826-46-5 α-hexyldibenzyl ketone 
• 111-66-0 oct-1-ene 
• 1240790-15-1 2,2'-(octane-1,2-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane) 
• 108-90-7 chlorobenzene 
• 108-86-1 bromobenzene 
• 110826-45-4 α-butylbenzyl benzyl ketone 
• 1188-92-7 Trihexylboran; Tri-n-hexylbor 
• 16548-51-9 benzylidenetriphenylarsenane 

Relevant articles and documents

A site-selective and stereospecific cascade Suzuki-Miyaura annulation of alkyl 1,2-bisboronic esters and 2,2′-dihalo 1,1′-biaryls

A cascade Suzuki-Miyaura cross-coupling giving rise to 9,10-dihydrophenanthrenes has been developed. Using biaryls with unsymmetrical substitution-pattern full site-selectivity was observed. Furthermore, this cross-coupling of an alkyl 1,2-bisboronic pinacol ester proceeds through the challenging coupling of a secondary boronate with complete stereoretention.

Norrish Type I and Type II Reactions of Ketones as Photochemical Probes of the Interior of Zeolites

The Norrish type I and type II reactions of alkylbenzoin ethers, alkyldeoxybenzoins and α-alkyldibenzyl ketones included within the microporous structures of zeolites X and Y have been investigated.Product distributions varied significantly from that observed in benzene.In addition, it differed between various alkali-metal cation-exchanged samples.These variations are interpreted to result from the restriction offered by the zeolite micropores on the motions of the adsorbed organic molecule.Although this study is restricted to ketones, the knowledge gained is expected to be of general value.

Modification of Photochemical Reactivity by Cyclodextrin Complexation: A Remarkable Effect on the Photobehavior of α-Alkyldibenzyl Ketones

The Norrish type I and type II reactions of cyclodextrin-included α-alkyldibenzyl ketones have been investigated in the aqueous solution and in the solid state.The photolysis of solid cyclodextrin complexes led to a single product, diphenylethane (AB), and that of complexes in the aqueous solution resulted in a product arising from the rerrangement of α-alkyldibenzyl ketones.Conformational and super-cage effects are proposed to be responsible for the dramatic alteration observed in the above photobehavior.The difference in the product distribution between solid and solution complexes is attributed to the differences in the restriction imposed by the host on the translational motions of the geminate radical pairs.