94759-76-9

Basic information

• Product Name: 1,1-Dimethyl-2,6-diphenyl-cyclohexandiol-(2,6)
• Synonyms: 1,1-Dimethyl-2,6-diphenyl-cyclohexandiol-(2,6)
• CAS NO: 94759-76-9
• Molecular Weight: 296.409
• Mol File: 94759-76-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,1-Dimethyl-2,6-diphenyl-cyclohexandiol-(2,6)(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1-Dimethyl-2,6-diphenyl-cyclohexandiol-(2,6)(94759-76-9)
• EPA Substance Registry System: 1,1-Dimethyl-2,6-diphenyl-cyclohexandiol-(2,6)(94759-76-9)

Safety Data

• Hazardous Substances Data: 94759-76-9(Hazardous Substances Data)

Upstream product

• 562-13-0 2,2-dimethyl-1,3-cyclohexanedione 
• 591-51-5 phenyllithium 

Relevant articles and documents

A study on the scope of the photochemical 1,3-migration of oximino groups in β,γ-unsaturated oximes and oxime derivatives

While the aza-di-π-methane rearrangement is the normal photoreactive behaviour of β,γ-unsaturated imines and oxime acetates, the results obtained in this study show that 1,3-migrations of acetoxyimino groups in β,γ-unsaturated oxime acetates takes place only when all the parameters are correct. The rearrangement takes place when there is a quaternary carbon separating the two π-systems and when one of the radical centres in the intermediate cyclobutyl 1,4-biradical is stabilized by conjugation with a phenyl ring. Suppression of the free rotor effect also helps to promote the reaction. These criteria are fulfilled in compounds 1a and 7a. The reaction was extended to the β,γ-unsaturated oximes 1b and 7b where again the 1,3-migration of the oximino group took place. Copyright 1996 by the Royal Society of Chemistry.