94934-06-2Relevant articles and documents
Preparation of Unsymmetrical Disulfides from Thioacetates and Thiosulfonates
Delarue Bizzini, Lorenzo,Zwick, Patrick,Mayor, Marcel
, p. 6956 - 6960 (2019)
A method for the transformation of organic thioacetates, a widely used functionality for the preparation of self-assembled monolayers on gold surfaces, into unsymmetrical disulfides is reported. Disulfides are readily immobilized on gold in contrast to thioacetates, which usually require a deprotection step prior to bonding to the metal surface. The potential of the method for the controlled preparation of unsymmetrical disulfides has been demonstrated with model compounds comprising several thioacetates, which were readily converted into the corresponding unsymmetrical disulfides.
Metal-free NaI/TBHP-mediated sulfonylation of thiols with sulfonyl hydrazides
Chen, Qian,Huang, Yulin,Wang, Xiaofeng,Wu, Jiawei,Yu, Guodian
, p. 1713 - 1719 (2018/03/21)
A highly efficient sulfonylation of thiols has been achieved through the metal-free NaI/TBHP-mediated cross-coupling of sulfonyl hydrazides and thiols at room temperature. This method provides a convenient and practical route to thiosulfonates in 84-99% y