94936-35-3

Basic information

• Product Name: 1-Piperidinecarboxylicacid,5-amino-2,3,4-trihydroxy-,methylester,(2alpha,3beta,4beta,5alpha)-(9CI)
• Synonyms: 1-Piperidinecarboxylicacid,5-amino-2,3,4-trihydroxy-,methylester,(2alpha,3beta,4beta,5alpha)-(9CI)
• CAS NO: 94936-35-3
• Molecular Formula: C7H14N2O5
• Molecular Weight: 0
• Product Categories: AMINOACID
• Mol File: 94936-35-3.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1-Piperidinecarboxylicacid,5-amino-2,3,4-trihydroxy-,methylester,(2alpha,3beta,4beta,5alpha)-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Piperidinecarboxylicacid,5-amino-2,3,4-trihydroxy-,methylester,(2alpha,3beta,4beta,5alpha)-(9CI)(94936-35-3)
• EPA Substance Registry System: 1-Piperidinecarboxylicacid,5-amino-2,3,4-trihydroxy-,methylester,(2alpha,3beta,4beta,5alpha)-(9CI)(94936-35-3)

Safety Data

• Hazardous Substances Data: 94936-35-3(Hazardous Substances Data)

Upstream product

• 94936-26-2 methyl 2-benzyloxycarbonyl-7,8-dihydroxy-3-oxa-2,5-diazabicyclo<2.2.2>octane-5-carboxylate 
• 33707-36-7 1-(methoxycarbonyl)-1,2-dihydropyridine 
• 94936-50-2 (1S,4R)-3-Oxa-2,5-diaza-bicyclo[2.2.2]oct-7-ene-2,5-dicarboxylic acid 2-benzyl ester 5-methyl ester 

Relevant articles and documents

Syntheses of Diamino-dideoxylyxose Derivatives using Acylnitroso Dienophiles

N-Acylnitroso derivatives 6 which were prepared by in-situ oxidation of the corresponding hydroxamic acids 5 reacted instantaneously and in high yields with dihydropyridine 4.The Diels-Alder adducts 8 were formed regiospecifically with the acylnitroso dienophiles 6a-c, whereas the dienophiles 6d-f gave mixtures of both regioisomers 7 and 8.These and some other results were best explained by the FMO theory.The Diels-Alder adducts 7 and 8 gave the corresponding 'anti'-cis-glycols when reacted with OsO4/N-methylmorpholine N-oxide.Hydrogenolysis of the N-O bond folloved by peracetylation led to the expected aminolyxose derivatives 14 and 16.A similar sequence, using 4 and the hydroxamic-acid derivative 18 of (+)-D-mandelic acid led, with a poor assymmetric induction, to a mixture of the expected optically active aminolyxose compounds 19A/19B.