95012-36-5

Basic information

• Product Name: Rh((C₆H₅)2PC₆H₄NH₂)2⁽¹⁺⁾*CH₃C₆H₄SO₃^(1-)
• CAS NO: 95012-36-5
• Molecular Weight: 828.713
• Mol File: 95012-36-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Rh((C₆H₅)2PC₆H₄NH₂)2⁽¹⁺⁾*CH₃C₆H₄SO₃^(1-)(CAS DataBase Reference)
• NIST Chemistry Reference: Rh((C₆H₅)2PC₆H₄NH₂)2⁽¹⁺⁾*CH₃C₆H₄SO₃^(1-)(95012-36-5)
• EPA Substance Registry System: Rh((C₆H₅)2PC₆H₄NH₂)2⁽¹⁺⁾*CH₃C₆H₄SO₃^(1-)(95012-36-5)

Safety Data

• Hazardous Substances Data: 95012-36-5(Hazardous Substances Data)

Upstream product

• 12092-47-6 di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium 
• 4124-42-9 ammonium p-toluenesulfonate 
• 65423-44-1 (2-diphenylphosphino)benzeneamine 

Relevant articles and documents

Reaction of Cl with Air; Characterisation of the Products by X-ray Structure Analysis of cis and trans-*MeCN

The chlorohydridorhodium(III) complex of (o-diphenylphosphinophenyl)amine, Cl (1a), formed by oxidative addition of HCl to (6), containing an amino- and amido-donor group, and the trans-dichloro-complex (8).Crystals of (6) are monoclinic, space group P21/n, with a=17.153(3), b=18.667(3), c=9.891(2) Angstroem, β=91.77(3) deg, and Z=4.Blocked full-matrix refinement using 3 501 unique data =3?(I), 3 gave R=0.0487, R'=0.051.Complex (8) crystallises, with a molecule of acetonitril as solvate, in the monoclinic space group I2/c with a=18.394(4), b=14.380(3), c=16.378(3) Angstroem, β=96.67(4) deg, and Z=4.Blocked full-matrix refinement of 2741 reflections with I>=3?(I) (32 symmetry.A mechanism for the reaction is proposed which involves peroxo- and hydrogenperoxo-species.