95043-55-3

Basic information

• Product Name: Oxirane, [(2-propenyloxy)methyl]-, (2S)-
• CAS NO: 95043-55-3
• Molecular Formula: C6H10O2
• Molecular Weight: 114.144
• Mol File: 95043-55-3.mol
• Article Data: 17

Chemical Properties

• CAS DataBase Reference: Oxirane, [(2-propenyloxy)methyl]-, (2S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Oxirane, [(2-propenyloxy)methyl]-, (2S)-(95043-55-3)
• EPA Substance Registry System: Oxirane, [(2-propenyloxy)methyl]-, (2S)-(95043-55-3)

Safety Data

• Hazardous Substances Data: 95043-55-3(Hazardous Substances Data)

Upstream product

• 106-95-6 allyl bromide 
• 57044-25-4 (R)-oxiranemethanol 
• 106-92-3 Allyl glycidyl ether 
• 62-53-3 aniline 
• 557-40-4 Allyl ether 
• 128495-89-6 3-(allyloxy)-2-acetoxypropyl p-toluenesulfonate 
• 152752-38-0 2-hydroxy-3-allyloxypropyl 4-toluenesulfonate 
• 123-34-2 3-allyloxy-1,2-propanediol 
• 18657-14-2 (4R)-2,2-dimethyl-4-{[(prop-2-en-1-yl)oxy]methyl}-1,3-dioxolane 
• 56083-15-9 (S)-4-((allyloxy)methyl)-2,2-dimethyl-1,3-dioxolane 
• 123-34-2 (R)-3-allyloxypropane-1,2-diol 
• 71026-29-4 (S)-1-O-Trityl-3-O-allyl-glycerol 
• 94985-45-2 3-O-allyl-2-O-p-toluenesulfonyl-sn-glycerol 
• 70987-78-9 (S)-Glycidyl tosylate 

Downstream Products

• 94985-38-3 1-O-allyl-2-O-benzyl-3-deoxy-2(S)-glycerol 
• 117606-90-3 (R)-1-O-allyl-3-O-benzylglycerol 

Relevant articles and documents

Aromatic Donor-Acceptor Interaction-Based Co(III)-salen Self-Assemblies and Their Applications in Asymmetric Ring Opening of Epoxides

Aromatic donor-acceptor interaction as the driving force to assemble cooperative catalysts is described. Pyrene/naphthalenediimide functionalized Co(III)-salen complexes self-assembled into bimetallic catalysts through aromatic donor-acceptor interactions and showed high catalytic activity and selectivity in the asymmetric ring opening of various epoxides. Control experiments, nuclear magnetic resonance (NMR) spectroscopy titrations, mass spectrometry measurement, and X-ray crystal structure analysis confirmed that the catalysts assembled based on the aromatic donor-acceptor interaction, which can be a valuable noncovalent interaction in supramolecular catalyst development.

Flexible tetrahydropyran synthesis from homopropargylic alcohols using sequential Pd-Au catalysis

A flexible synthetic method toward highly substituted tetrahydropyran is reported. The key transformation involves atom-efficient sequential metal catalysis consisting of Pd-catalyzed addition of homopropargylic alcohols to alkoxyallene and the subsequent

Azidolysis of epoxides catalysed by the halohydrin dehalogenase from Arthrobacter sp. AD2 and a mutant with enhanced enantioselectivity: an (S)-selective HHDH

Halohydrin dehalogenase from Arthrobacter sp. AD2 catalysed azidolysis of epoxides with high regioselectivity and low to moderate (S)-enantioselectivity (E?=?1–16). Mutation of the asparagine 178 to alanine (N178A) showed increased enantioselectivity towards styrene oxide derivatives and glycidyl ethers. Conversion of aromatic epoxides was catalysed by HheA-N178A with complete enantioselectivity, however the regioselectivity was reduced. As a result of the enzyme-catalysed reaction, enantiomerically pure (S)-β-azido alcohols and (R)-α-azido alcohols (ee???99%) were obtained.