95068-22-7Relevant articles and documents
[Fp*Fc][PF6]: A remarkable non-symmetric dinuclear cation in a very stable mixed-valent state
Argouarch, Gilles,Grelaud, Guillaume,Roisnel, Thierry,Humphrey, Mark G.,Paul, Frédéric
, p. 218 - 223 (2017)
We report herein dicarbonyl(pentamethylcyclopentadienyl)(ferroceniumyl)iron hexafluorophosphate, which contains a dimetallic cation with a remarkably stable mixed-valent (MV) structure and unexpected redox features. The electronic structure of this compound is discussed in the light of the existing Hush model, which suggests an unusually strong electronic coupling between the two iron centers, despite the non-symmetric environment of the metallic centers. End-to-end charge delocalization is not the main contributor to the extra-large stability of this MV complex, which originates from electronic effects other than the energetic difference between the two MV redox isomers (ΔG0). This open-shell derivative has also been briefly tested as a catalyst in the reductive etherification of aldehydes by hydrosilanes.
ANTI-INFLAMMATORY COMPOUND HAVING INHIBITORY ACTIVITY AGAINST MULTIPLE TYROSINE KINASES AND PHARMACEUTICAL COMPOSITION CONTAINING SAME
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Paragraph 0312-0314, (2013/03/28)
The present invention is for the anti-inflammatory compounds that have an inhibitory activity against protein tyrosine kinases and their pharmaceutical composition(s) containing the compound as the active ingredient. Since the compounds of the present invention can inhibit multiple protein kinases associated with inflammatory diseases and immune disorders, they are useful for their prevention or treatment.
Highly efficient indium-catalyzed chemoselective allylation-etherification and reductive etherification of aromatic aldehydes with functional silanes
Yang, Ming-Song,Xu, Li-Wen,Qiu, Hua-Yu,Lai, Guo-Qiao,Jiang, Jian-Xiong
, p. 253 - 256 (2008/03/30)
Indium(III) chloride is an effective Lewis acid catalyst for one-pot allylation-etherification and reductive etherification of aromatic aldehydes with functional silanes, allyltriethoxysilane, and triethoxysilane, at room temperature to afford corresponding ethers in excellent yields. Additionally, the InCl3-catalyzed reactions in the presence of TMSCl offer significant advantages in its ease of working-up for the preparation of unsymmetrical ethers under mild conditions.