95068-98-7

Basic information

• Product Name: 3,4,6-tri-O-acetyl-2-C:1-N-carbonyl-2-deoxy-N-(p-tolylsulfonyl)-α-D-glucopyranosylamine
• Synonyms: 3,4,6-tri-O-acetyl-2-C:1-N-carbonyl-2-deoxy-N-(p-tolylsulfonyl)-α-D-glucopyranosylamine
• CAS NO: 95068-98-7
• Molecular Weight: 469.469
• Mol File: 95068-98-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3,4,6-tri-O-acetyl-2-C:1-N-carbonyl-2-deoxy-N-(p-tolylsulfonyl)-α-D-glucopyranosylamine(CAS DataBase Reference)
• NIST Chemistry Reference: 3,4,6-tri-O-acetyl-2-C:1-N-carbonyl-2-deoxy-N-(p-tolylsulfonyl)-α-D-glucopyranosylamine(95068-98-7)
• EPA Substance Registry System: 3,4,6-tri-O-acetyl-2-C:1-N-carbonyl-2-deoxy-N-(p-tolylsulfonyl)-α-D-glucopyranosylamine(95068-98-7)

Safety Data

• Hazardous Substances Data: 95068-98-7(Hazardous Substances Data)

Upstream product

• 4083-64-1 Tosyl isocyanate 
• 2873-29-2 D-glucal triacetate 

Downstream Products

• 95069-02-6 Acetic acid (2R,3S,4R,5R,6R)-3-acetoxy-2-acetoxymethyl-6-ethoxy-5-(toluene-4-sulfonylaminocarbonyl)-tetrahydro-pyran-4-yl ester 
• 2873-29-2 D-glucal triacetate 
• 95069-01-5 Acetic acid (2R,3S,4R,5R,6R)-3-acetoxy-2-acetoxymethyl-6-methoxy-5-(toluene-4-sulfonylaminocarbonyl)-tetrahydro-pyran-4-yl ester 

Relevant articles and documents

HIGH-PRESSURE (2+2)CYCLOADDITION OF TOLUENE-4-SULPHONYL ISOCYANATE TO GLYCALS

High-pressure (2+2)cycloaddition of toluene-4-sulphonyl isocyanate to glycals is examined.Reactions proceed regiospecifically to afford single products in case of all 3-substituted glycals.Upon heating or even after standing at room temperature adducts undergo retro-addition to give starting glycals.Various aspects of the cycloaddition are discussed, especially retro-reaction and rearrangement of β-lactams to α,β-unsaturated amides.