95087-00-6Relevant articles and documents
Synthesis of L-vancosamine derivatives from methyl α-D- mannopyranoside
Hsu, Day-Shin,Matsumoto, Takashi,Suzuki, Keisuke
, p. 469 - 471 (2007/10/03)
Concise synthesis of L-vancosamine, the amino sugar constituent of vancomycin and other antibiotics, has been achieved. The key steps include (1) stereoselective addition of methylcerium reagent to oximino ether, and (2) stereoselective hydrogenation of 5