951133-52-1Relevant articles and documents
Highly diastereoselective Katsuki-Jacobsen oxidation-epoxidation of α-silyloxy sulfinyl dienes: Synthetic applications
De La Pradilla, Roberto Fernández,Castellanos, Alejandro,Osante, I?aki,Colomer, Ignacio,Sánchez, Mateo I.
supporting information; experimental part, p. 170 - 181 (2009/04/18)
(Chemical Equation Presented) Katsuki-Jacobsen oxidation-epoxidation of acyclic α-silyloxy sulfinyl dienes, followed by acid-promoted cyclization, leads to 2,5-trans-sulfonyl dihydrofurans with good selectivities. As an application, the formal syntheses of (6S,7S,9R,10R)- and (6S,7S,9S,10S)-6,9- epoxynonadec-18-ene-7,10-diols is reported.