951133-55-4

Basic information

• Product Name: (+)-(5S,S(S))-(2E)-[4-(p-tolylsulfinyl)deca-1,3-dien-5-yloxy]trihexylsilane
• Synonyms: (+)-(5S,S(S))-(2E)-[4-(p-tolylsulfinyl)deca-1,3-dien-5-yloxy]trihexylsilane
• CAS NO: 951133-55-4
• Molecular Weight: 575.028
• Mol File: 951133-55-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (+)-(5S,S(S))-(2E)-[4-(p-tolylsulfinyl)deca-1,3-dien-5-yloxy]trihexylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-(5S,S(S))-(2E)-[4-(p-tolylsulfinyl)deca-1,3-dien-5-yloxy]trihexylsilane(951133-55-4)
• EPA Substance Registry System: (+)-(5S,S(S))-(2E)-[4-(p-tolylsulfinyl)deca-1,3-dien-5-yloxy]trihexylsilane(951133-55-4)

Safety Data

• Hazardous Substances Data: 951133-55-4(Hazardous Substances Data)

Upstream product

• 951133-45-2 (+)-(5S,S(S))-(4E)-4-(p-tolylsulfinyl)deca-1,3-dien-5-ol 
• 3634-67-1 trihexylsilyl chloride 
• 951133-73-6 (R)-(1,3-Butadienyl)-p-tolyl-sulfoxid 
• 66-25-1 hexanal 

Downstream Products

• 1092556-41-6 C₃₅H₆₂O₄SSi 
• 951133-94-1 (+)-(2S,3S,5R)-3-phenylcarbonyloxy-5-hydroxymethyl-2-pentyl-tetrahydrofuran 
• 128707-15-3 (2R,4S,5S)-tetrahydro-4-hydroxy-5-pentyl-2-furfuraldehyde (benzoate) 
• 951133-93-0 (+)-(2S,3S,5R)-5-(tert-butyldimethylsilyloxymethyl)-3-phenylcarbonyloxy-2-pentyl-tetrahydrofuran 
• 951133-90-7 (-)-(2S,3S,4S,5S)-2-(tert-butyldimethylsilyloxymethyl)-3,4-epoxy-5-pentyl-4-(p-tolylsulfonyl)tetrahydrofuran 
• 951133-89-4 (-)-(2R,5S)-2-(tert-butyldimethylsilyloxymethyl)-5-pentyl-4-(p-tolylsulfonyl)-2,5-dihydrofuran 
• 1092556-09-6 (-)-(2S,5S)-2-(tert-butyldimethylsilyloxymethyl)-5-pentyl-4-(p-tolylsulfonyl)-2,5-dihydrofuran 

Relevant articles and documents

Katsuki-Jacobsen oxidation-epoxidation of α-silyloxy sulfinyl dienes: application to the formal synthesis of (6S,7S,9R,10R)-6,9-epoxynonadec-18-ene-7,10-diol

The Katsuki-Jacobsen oxidation-epoxidation of acyclic α-silyloxy sulfinyl dienes, followed by acid-promoted cyclization, leads to 2,5-trans sulfonyl dihydrofurans with good selectivities. As an application, the formal synthesis of (6S,7S,9R,10R)-6,9-epoxy