95127-15-4Relevant articles and documents
Investigation of the mechanism for the preparation of 6-phenyl-2,4- dioxotetrahydropyrans by the potassium carbonate promoted condensation between acetoacetate esters and benzaldehyde
Andersh, Brad,Nguyen, Elizabeth T.,Van Hoveln, Ryan J.,Kemmerer, Dylan K.,Baudo, David A.,Graves, Jessica A.,Roark, Mollie E.,Bosma, Wayne B.
, p. 4563 - 4567 (2013/06/05)
Treatment of benzaldehyde and an acetoacetate ester with potassium carbonate in an alcohol solvent proceeds via γ-C-alkylation rather than α-C-alkylation resulting in the formation of 6-phenyl-2,4- dioxotetrahydropyran. Based upon results from deuterium e