95149-22-7

Basic information

• Product Name: (p-CH₃C₆H₄)2BiC₆H₄-p-Cl
• Synonyms: (p-CH₃C₆H₄)2BiC₆H₄-p-Cl
• CAS NO: 95149-22-7
• Molecular Weight: 502.796
• Mol File: 95149-22-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (p-CH₃C₆H₄)2BiC₆H₄-p-Cl(CAS DataBase Reference)
• NIST Chemistry Reference: (p-CH₃C₆H₄)2BiC₆H₄-p-Cl(95149-22-7)
• EPA Substance Registry System: (p-CH₃C₆H₄)2BiC₆H₄-p-Cl(95149-22-7)

Safety Data

• Hazardous Substances Data: 95149-22-7(Hazardous Substances Data)

Upstream product

• 873-77-8 (4-chlorphenyl)magnesium bromide 
• 51752-29-5 bis(4-methylphenyl)bismuth chloride 
• 51833-36-4 4-chlorophenylmagnesium chloride 
• 34176-68-6 bis(4-methylphenyl)bismuth bromide 
• 121900-05-8 iodobis(4-methylphenyl)bismuthane 
• 7270-47-5 4-chlorophenylmagnesium iodide 
• 144773-75-1 {2-(tert-butylsulfonyl)phenyl}bis-(4-methylphenyl)bismuthine 
• 14774-78-8 4-chlorophenyl lithium 

Downstream Products

• 99-94-5 p-Toluic acid 
• 74-11-3 para-chlorobenzoic acid 

Relevant articles and documents

A New General Method for the Synthesis of Chiral Triarylbismuthines based on the Intramolecular Coordination by a Sulfonyl Group

Chiral triarylbismuthines 4 are synthesized by the sulfonyl-controlled selective iododearylation of 2, followed by reaction of the resulting iodobismuthine 3 with aryl Grignard reagents and are resolved into each pair of optical isomers; compounds 4 were readily converted into chiral bismuthines 5 of a more general type by nucleophilic substitution with aryllithium at the bismuth atom centre.