95187-63-6

Basic information

• Product Name: Benzeneacetonitrile, 4-chloro-a-(2-furanylmethylene)-, (Z)-
• CAS NO: 95187-63-6
• Molecular Formula: C13H8ClNO
• Molecular Weight: 229.666
• Mol File: 95187-63-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzeneacetonitrile, 4-chloro-a-(2-furanylmethylene)-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzeneacetonitrile, 4-chloro-a-(2-furanylmethylene)-, (Z)-(95187-63-6)
• EPA Substance Registry System: Benzeneacetonitrile, 4-chloro-a-(2-furanylmethylene)-, (Z)-(95187-63-6)

Safety Data

• Hazardous Substances Data: 95187-63-6(Hazardous Substances Data)

Upstream product

• 98-01-1 furfural 
• 140-53-4 p-chlorobenzyl cyanide 
• 98-02-2 2-thiolomethyl-furan 
• 108-88-3 toluene 
• 104-83-6 1-Chloro-4-(chloromethyl)benzene 

Downstream Products

• 782-21-8 2-(4-chloro-phenyl)-3-furan-2-yl-propionitrile 

Relevant articles and documents

Direct C–S Bond Functionalization of Benzyl Mercaptan

Cleavage of a C–S bond of benzyl mercaptan led to formation of a new C–C bond during (Z)-selective alkenylation of nitriles using 1,10-phenanthroline as organocatalyst and tBuOK as a base. Furthermore, we have shown that the cascaded functionalization of benzylic C–S and aryl–halide bonds could be done in one pot. 1H NMR study and kinetic experiments also helped to establish the mechanism of the reaction.

1H-NMR, Ultraviolet and Infrared Spectra of Some (Z)-α-(Phenyl)-β-(2-furyl), -(2-pyrrolyl) and -(N-methyl-2-pyrrolyl)acrylonitriles

The 1H-nmr data of some (Z)-α-(p-substitued-phenyl)-β-(2-furyl), -(2-pyrrolyl), and -(N-methyl-2-pyrrolyl)acrylonitriles have been investigated to indicate the preferred conformation and to establish the conformational preferences of the β-heterocyclic ri