95188-04-8

Basic information

• Product Name: Benzenamine, N-[(2,2-dimethylcyclopropyl)methylene]-
• CAS NO: 95188-04-8
• Molecular Formula: C12H15N
• Molecular Weight: 173.258
• Mol File: 95188-04-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzenamine, N-[(2,2-dimethylcyclopropyl)methylene]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N-[(2,2-dimethylcyclopropyl)methylene]-(95188-04-8)
• EPA Substance Registry System: Benzenamine, N-[(2,2-dimethylcyclopropyl)methylene]-(95188-04-8)

Safety Data

• Hazardous Substances Data: 95188-04-8(Hazardous Substances Data)

Upstream product

• 26119-44-8 2,2-dimethylcyclopropane-1-carbaldehyde 
• 62-53-3 aniline 
• 5722-11-2 rac-2,2-dimethylcyclopropanecarbonitrile 

Downstream Products

• 95188-06-0 N-(2,2-dimethylcyclopropyl)methylaniline 
• 58008-11-0 N-(4-methylpentyl)aniline 

Relevant articles and documents

NADH MODELS-19 CYCLOPROPANE RING AS A CHEMICAL PROBE IN THE STUDY OF THE MECHANISM OF HYDROGEN TRANSFER BY 1,4-DIHYDROPYRIDINE DERIVATIVES

N-(Cyclopropylmethylene)phenylamines (1a-c), cyclopropyl 2-pyridyl ketones (5a-c) and ethyl cyclopropylmethylenepyruvate (14) have been subjected to reduction by 1,4-dihydropyridines in the presence of magnesium ions, and by tin hydrides.The reactions with 1,4-dihydropyridines do not involve cleavage of the three-membered ring in the reduction step.The observed acyclic product from 2-pyridyl 2,2-dimethylcyclopropyl ketone (5b) is a consequence of ring cleavage prior to reduction of the carbonyl function.In contrast, reduction of 1a-c and 5a-c by tin hydrides leads to products in which the cyclopropane moiety has undergone ring-opening.These findings support a hydride transfer mechanism for reductions with NADH models.