95196-99-9

Basic information

• Product Name: Sulfamide, N,N'-bis(4-bromophenyl)-
• CAS NO: 95196-99-9
• Molecular Formula: C12H10Br2N2O2S
• Molecular Weight: 406.098
• Mol File: 95196-99-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Sulfamide, N,N'-bis(4-bromophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Sulfamide, N,N'-bis(4-bromophenyl)-(95196-99-9)
• EPA Substance Registry System: Sulfamide, N,N'-bis(4-bromophenyl)-(95196-99-9)

Safety Data

• Hazardous Substances Data: 95196-99-9(Hazardous Substances Data)

Upstream product

• 106-40-1 4-bromo-aniline 
• 587-14-4 N,N'-diphenylsulfamide 
• 7726-95-6 bromine 
• 71-43-2 benzene 
• 67-66-3 chloroform 

Downstream Products

• 103-88-8 4-bromoacetanilide 
• 7150-24-5 1-(4-bromophenylazo)-2-naphthol 

Relevant articles and documents

Electrochemical synthesis of sulfamides

Herein we demonstrate the first electrochemical synthesis protocol of symmetrical sulfamides directly from anilines and SO2mediated by iodide. Sulfamides are an emerging functional group in drug design. Highlights are the direct use of SO2from a stock solution and no necessity of any supporting electrolyte. Overall, the reaction has been demonstrated for 15 examples with yields up to 93%.

Vicinal Diamination of Arenes with Domino Aryne Precursors

Vicinal diamination of domino aryne precursors was achieved with sulfamides. The reaction proceeds through a two-aryne pathway, accepting two N-nucleophiles at the 1,2-positions of an arene ring. Symmetrical and unsymmetrical diaminobenzenes were readily obtained.

Sulfamides and sulfamide polymers directly from sulfur dioxide

SO2 gas is effectively used for the preparation of N,N′-diarylsulfamides and shape-persistent sulfamide polymers, which utilize a network of intermolecular N-H...O=S hydrogen bonds to self-assemble into soft porous materials. The Royal Society of Chemistry 2006.