95246-09-6

Basic information

• Product Name: (4,7-diphenyl-1,10-phenanthroline)palladium(II) acetate
• Synonyms: (4,7-diphenyl-1,10-phenanthroline)palladium(II) acetate
• CAS NO: 95246-09-6
• Molecular Weight: 556.914
• Mol File: 95246-09-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (4,7-diphenyl-1,10-phenanthroline)palladium(II) acetate(CAS DataBase Reference)
• NIST Chemistry Reference: (4,7-diphenyl-1,10-phenanthroline)palladium(II) acetate(95246-09-6)
• EPA Substance Registry System: (4,7-diphenyl-1,10-phenanthroline)palladium(II) acetate(95246-09-6)

Safety Data

• Hazardous Substances Data: 95246-09-6(Hazardous Substances Data)

Upstream product

• 1662-01-7 bathophenanthroline 
• 3375-31-3 palladium diacetate 

Downstream Products

• 157378-10-4 Pd (4,7-diphenyl-1,10-phenantroline) bis(trifluoroacetate) 

Relevant articles and documents

Cationic palladium(II) complexes as catalysts for the oxidation of terminal olefins to methyl ketones using hydrogen peroxide

Ligated Pd(II) complexes have been studied for the catalytic oxidation of terminal olefins to their corresponding methyl ketones. The method uses aqueous hydrogen peroxide as the terminal oxidant; a sustainable and readily accessible oxidant. The choice of ligand, counterion and solvent all have a significant effect on catalytic performance and we were able to develop systems which perform well for these challenging oxidations.

Synthesis and Characterization of Monochelated Carboxylatopalladium(II) Complexes with Nitrogen-donor Chelating Ligands. Crystal Structures of Diacetato(1,10-phenanthroline)- and Diacetato(2,9-dimethyl-1,10-phenanthroline)-palladium(II)

Two series of monochelated carboxylatopalladium(II) complexes of general formula and 2,9 protons in the phenanthroline series, and those of H6,6 in the bipyridine one, are excellent probes for the evaluation of the environment of the palladium atom.The crystal structures of , *0.40CH2Cl2 and *0.25CHCl3 (2,9-dmphen=2,9-dimethyl-1,10-phenanthroline) have been determined.The co-ordination geometry around palladium is square planar in all the structures, but significant deviations from the idealized geometry occur in the last two in order to relieve the interligand contacts.These monochelated carboxylatopalladium(II) complexes are active catalysts in carbon monoxide-olefin copolymerization.Some preliminary results on their catalytic activity are also reported.