95249-01-7

Basic information

• Product Name: Benzene, 1-chloro-2-(dodecyloxy)-
• CAS NO: 95249-01-7
• Molecular Formula: C18H29ClO
• Molecular Weight: 296.881
• Mol File: 95249-01-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, 1-chloro-2-(dodecyloxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-chloro-2-(dodecyloxy)-(95249-01-7)
• EPA Substance Registry System: Benzene, 1-chloro-2-(dodecyloxy)-(95249-01-7)

Safety Data

• Hazardous Substances Data: 95249-01-7(Hazardous Substances Data)

Upstream product

• 95-57-8 2-monochlorophenol 
• 143-15-7 1-dodecylbromide 
• 35021-68-2 dodecyloxybenzene 

Downstream Products

• 35021-68-2 dodecyloxybenzene 

Relevant articles and documents

Visible light-promoted reductive transformations of various organic substances by using hydroxyaryl-substituted benzimidazolines and bases

Visible light promoted reduction reactions of organohalides, sulfonamides, organonitriles and epoxy ketones were performed using 1,3-dimethylbenzimidazolines possessing 2-hydroxynaphthyl or 2-hydroxyphenyl substituents (HOAr-DMBIH) as photo-reductants. Xe or Hg–Xe lamp through an appropriate glass-filter (λ>390 nm) and a household white light-emitting diode were used as light sources. In these reactions, reductive cleavages of carbon[sbnd]halogen, nitrogen[sbnd]sulfur, carbon[sbnd]carbon (nitrile) and carbon[sbnd]oxygen bonds take place. Bases exert significant effects on the progress of these reactions in a manner that depends on the nature of the substrate. Addition of 1,8-diazabicyclo[5.4.0]undec-7-ene as well as potassium t-butoxide significantly accelerates photo-reduction reactions of organohalides, sulfonamides and organonitriles while the decomposition of formed hydroxy ketones occurs in reactions of epoxy ketones. Single electron transfer from the photo-excited states of benzimidazolines (HOAr-DMBIH) or their deprotonated analogues (?OAr-DMBIH) to the substrates is proposed to initiate these reactions.

SELECTIVITY OF AROMATIC CHLORINATION REACTIONS WITHIN A REVERSED-PHASE LIQUID CHROMATOGRAPHY COLUMN

Substrate selectivity was obtained in the chlorination of a series of n-alkyl phenyl ethers by chlorine water on a reversed-phase high performance liquid chromatography column at 25 deg C.