95408-38-1 Usage
Description
1-DIPHENYLPHOSPHINO-1'-(DI-TERT-BUTYLPH& is a phosphine ligand with a diphenylphosphino group and a di-tert-butylphenyl group. It is known for its stability and versatility in various catalytic applications.
Used in Chemical Synthesis Industry:
1-DIPHENYLPHOSPHINO-1'-(DI-TERT-BUTYLPH& is used as a catalyst in the microwave-assisted preparation of aryl-alkyl ethers via palladium-catalyzed Hiyama coupling of alkoxysilanes with aryl bromides or aryl chlorides. This application allows for efficient and selective formation of aryl-alkyl ether bonds, which are important in the synthesis of various organic compounds.
Used in Nickel Catalysis:
1-DIPHENYLPHOSPHINO-1'-(DI-TERT-BUTYLPH& is used as a ligand for catalytic isomerization of methylbutenenitrile via nickel systems. This application enables the conversion of methylbutenenitrile to other valuable compounds, such as isobutenenitrile, which can be further used in the production of various chemicals and materials.
Used in Ruthenium Catalysis:
1-DIPHENYLPHOSPHINO-1'-(DI-TERT-BUTYLPH& is used as a ligand for ruthenium alkylidene complexes, which are employed in the catalysis of metathesis reactions and catalytic norbornene polymerization. This application contributes to the development of new polymer materials and the synthesis of complex organic molecules through metathesis reactions.
Check Digit Verification of cas no
The CAS Registry Mumber 95408-38-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,5,4,0 and 8 respectively; the second part has 2 digits, 3 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 95408-38:
(7*9)+(6*5)+(5*4)+(4*0)+(3*8)+(2*3)+(1*8)=151
151 % 10 = 1
So 95408-38-1 is a valid CAS Registry Number.
95408-38-1Relevant articles and documents
Comparing the asymmetric dppf-type ligands with their semi-homologous counterparts
Vosáhlo, Petr,Císa?ová, Ivana,?těpni?ka, Petr
, p. 14 - 29 (2018/02/20)
Two series of asymmetric ferrocene diphosphines, namely the dppf-type ligands R2PfcPPh2 (protected as BH3 adducts; fc = ferrocene-1,1′-diyl) and their semi-homologous counterparts R2PfcCH2PPh2/s