95409-25-9

Basic information

• Product Name: 2-Butynal, 4-(phenylmethoxy)-
• CAS NO: 95409-25-9
• Molecular Formula: C11H10O2
• Molecular Weight: 174.199
• Mol File: 95409-25-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2-Butynal, 4-(phenylmethoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Butynal, 4-(phenylmethoxy)-(95409-25-9)
• EPA Substance Registry System: 2-Butynal, 4-(phenylmethoxy)-(95409-25-9)

Safety Data

• Hazardous Substances Data: 95409-25-9(Hazardous Substances Data)

Upstream product

• 91142-50-6 4-benzyloxy-2-butyn-1-ol 
• 4039-82-1 Benzyl propargyl ether 
• 68-12-2 N,N-dimethyl-formamide 
• 149125-61-1 methyl 4-(benzyloxy)-2-butynoate 
• 100-44-7 benzyl chloride 
• 50-00-0 formaldehyd 
• 444816-17-5 (4-benzyloxy-but-2-ynyloxy)-triethyl-silane 
• 444816-18-6 1-(benzyloxy)-4-[(tert-butyldimethylsilyl)oxy]-2-butyne 

Downstream Products

• 1138138-95-0 ethyl (E)-6-(benzyloxy)hex-2-en-4-ynoate 
• 252873-95-3 (R)-4-(3-Benzyloxy-prop-1-ynyl)-oxetan-2-one 
• 1229446-62-1 C₁₂H₁₁NO₃ 

Relevant articles and documents

Copper-Catalyzed Asymmetric Silylation of Propargyl Dichlorides: Access to Enantioenriched Functionalized Allenylsilanes

A copper-catalyzed silylation of propargyl dichlorides was developed to access chloro-substituted allenylsilanes under mild reaction conditions. Moreover, enantioenriched chloro-substituted allenylsilanes can be synthesized in moderate to high yields and good enantioselectivities with this protocol.

Asymmetric direct aldol reactions of acetoacetals catalyzed by a simple chiral primary amine

(Chemical Equation Presented) An asymmetric direct aldol reaction of acetoacetals is described. Under the catalysis of a simple chiral primary amine, the direct aldol reactions of acetoacetals occur exclusively on the γ-position to give vinylogous-type al

Facile cleavage of triethylsilyl (TES) ethers using o-lodoxybenzoic acid (IBX) without affecting tert-butyldimethylsilyl (TBS) ethers

(matrix presented) In DMSO cleavage of triethylsilyl (TES) ethers by o-iodoxybenzoic acid (IBX) was significantly faster than cleavage of tert-butyldimethylsilyl (TBS) ethers or further oxidation into carbonyl compounds. In most cases, TES protecting groups be removed in good to excellent yields within 1 h, whereas similar TBS protecting groups remained intact under the same conditions. The procedure also could be adapted for direct one-pot conversion of TES ethers into carbonyl compounds.