95443-61-1

Basic information

• Product Name: 1-(4-chlorophenyl)-4-methylpentan-1-ol
• CAS NO: 95443-61-1
• Molecular Weight: 212.719
• Mol File: 95443-61-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-(4-chlorophenyl)-4-methylpentan-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4-chlorophenyl)-4-methylpentan-1-ol(95443-61-1)
• EPA Substance Registry System: 1-(4-chlorophenyl)-4-methylpentan-1-ol(95443-61-1)

Safety Data

• Hazardous Substances Data: 95443-61-1(Hazardous Substances Data)

Upstream product

• 4548-78-1 (3-methylbutyl)magnesium bromide 
• 104-88-1 4-chlorobenzaldehyde 

Downstream Products

• 97492-93-8 Bernsteinsaeure-mono-<4-methyl-1-(4-chlor-phenyl)-pentylester> 

Relevant articles and documents

Regioselective Vinylation of Remote Unactivated C(sp3)?H Bonds: Access to Complex Fluoroalkylated Alkenes

Regioselective incorporation of a particular functional group into aliphatic sites by direct activation of unreactive C?H bonds is of great synthetic value. Despite advances in radical-mediated functionalization of C(sp3)?H bonds by a hydrogen-atom transfer process, the site-selective vinylation of remote C(sp3)?H bonds still remains underexplored. Reported herein is a new protocol for the regioselective vinylation of unactivated C(sp3)?H bonds. The remote C(sp3)?H activation is promoted by a C-centered radical instead of the commonly used N and O radicals. The reaction possesses high product diversity and synthetic efficiency, furnishing a plethora of synthetically valuable E alkenes bearing tri-/di-/mono-fluoromethyl and perfluoroalkyl groups.