95547-10-7

Basic information

• Product Name: Methanamine, N-[(2-bromophenyl)methylene]-
• CAS NO: 95547-10-7
• Molecular Formula: C8H8BrN
• Molecular Weight: 198.062
• Mol File: 95547-10-7.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Methanamine, N-[(2-bromophenyl)methylene]-(CAS DataBase Reference)
• NIST Chemistry Reference: Methanamine, N-[(2-bromophenyl)methylene]-(95547-10-7)
• EPA Substance Registry System: Methanamine, N-[(2-bromophenyl)methylene]-(95547-10-7)

Safety Data

• Hazardous Substances Data: 95547-10-7(Hazardous Substances Data)

Upstream product

• 593-51-1 methylamine hydrochloride 
• 6630-33-7 ortho-bromobenzaldehyde 
• 698-19-1 N-methyl-2-bromobenzylamine 
• 74-89-5 methylamine 

Downstream Products

• 698-19-1 N-methyl-2-bromobenzylamine 
• 1262325-10-9 4-(2-bromobenzylidene)-1,2-dimethyl-1H-imidazol-5(4H)-one 
• 620598-72-3 Acetic acid (S)-[(2-bromo-benzyl)-methyl-carbamoyl]-phenyl-methyl ester 

Relevant articles and documents

Enantioselective Reductive Coupling of Imines Templated by Chiral Diboron

We herein report a general, practical, and highly efficient method for asymmetric synthesis of a wide range of chiral vicinal diamines via reductive coupling of imines templated by chiral diboron. The protocol features high enantioselectivity and stereospecificity, mild reaction conditions, simple operating procedures, use of readily available starting materials, and a broad substrate scope. The method signifies the generality of diboron-enabled [3,3]-sigmatropic rearrangement.

Four-Electron Electrocyclic Ring-Opening/Intermolecular [4+2] Cycloadditions of α-Hydroxycyclobutenones: Stereoselective Synthesis of Multiple Substituted δ-Lactams

A four-electron electrocyclic ring-opening/intermolecular [4+2] cycloaddition of α-hydroxycyclobutenones is reported. The reaction represents the first example for the intermolecular cycloaddition of the extensively studied enol-ketene intermediate, and provides a new synthetic route to multiply substituted δ-lactams in high stereoselectivity.

Steric and electronic effects in capsule-confined green fluorescent protein chromophores

The turn-on of emission in fluorescent protein chromophores sequestered in an "octaacid" capsule is controlled by stereoelectronic effects described by a linear free energy relationship. The stereochemical effects are governed by both the positions and volumes of the aryl substituents, while the electronic effects, including ortho effects, can be treated with Hammett σ parameters. The use of substituent volumes rather than A values reflects packing of the molecule within the confines of the capsule.