95574-44-0

Basic information

• Product Name: Cyclohexanone, 4-hydroxy-2,2,5,5-tetramethyl-, (S)-
• CAS NO: 95574-44-0
• Molecular Formula: C10H18O2
• Molecular Weight: 170.252
• Mol File: 95574-44-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Cyclohexanone, 4-hydroxy-2,2,5,5-tetramethyl-, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone, 4-hydroxy-2,2,5,5-tetramethyl-, (S)-(95574-44-0)
• EPA Substance Registry System: Cyclohexanone, 4-hydroxy-2,2,5,5-tetramethyl-, (S)-(95574-44-0)

Safety Data

• Hazardous Substances Data: 95574-44-0(Hazardous Substances Data)

Upstream product

• 86838-54-2 2,2,5,5-tetramethyl-cyclohexane-1,4-dione 

Downstream Products

• 95910-59-1 (S)-4-(mesyloxy)-2,2,5,5-tetramethylcyclohexan-1-one 

Relevant articles and documents

STEREOSELECTIVE SYNTHESIS OF (1R,3S)-CIS-CHRYSANTHEMIC ACID THROUGH MICROBIOLOGICAL REDUCTION OF 2,2,5,5-TETRAMETHYL 1,4-CYCLOHEXANEDIONE.

An efficient, highly stereoselective synthesis of (1R,3S)-cis-chrysanthemic acid 6 is described.The crucial step of this synthesis was the microbiological reduction of dione 1 into (S)-ketol 2.

A Short, Efficient, Highly Selective Synthesis of (1R,3S)-cis-Chrysanthemic Acid through the Microbiological Reduction of 2,2,5,5-Tetramethyl-1,4-cyclohexanedione

A highly selective synthesis of (1R,3S)-cis-chrysanthemic acid (1a), a key intermediate in the industrial prepariation of major unnatural pyrethrinoid-type insecticides is reported. 2,2,5,5-Tetramethyl-1,4-cyclohexanedi