956101-42-1

Basic information

• Product Name: C₆H₅C₃H₄NC₂H₃OC₅H₉O₂
• Synonyms: C₆H₅C₃H₄NC₂H₃OC₅H₉O₂
• CAS NO: 956101-42-1
• Molecular Weight: 275.348
• Mol File: 956101-42-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₆H₅C₃H₄NC₂H₃OC₅H₉O₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₆H₅C₃H₄NC₂H₃OC₅H₉O₂(956101-42-1)
• EPA Substance Registry System: C₆H₅C₃H₄NC₂H₃OC₅H₉O₂(956101-42-1)

Safety Data

• Hazardous Substances Data: 956101-42-1(Hazardous Substances Data)

Upstream product

• 106625-69-8 ethyl (E)-3-phenyl-2-propenyl carbonate 
• 120157-98-4 N-(tert-butyloxycarbonyl)glycine 

Downstream Products

• 956101-46-5 tert-butyl [(1S)-1-phenylprop-2-en-1-yl]imidocarbonate 

Relevant articles and documents

Iridium(I)-catalyzed regio- and enantioselective allylic amidation

Ir(I)-catalyzed intermolecular allylic amidation of ethyl allyl carbonates with soft nitrogen nucleophiles under completely 'salt-free' conditions is described. A combination of [Ir(COD)Cl]2, a chiral phosphoramidite ligand L*, and DBU as a base in THF effects the reaction. The reaction appears to be quite general, accommodating a wide variety of R-groups and soft nitrogen nucleophiles, and proceeds with excellent regio- and enantioselectivities to afford the branched N-protected allylic amines. The developed reaction was conveniently utilized in the asymmetric synthesis of N-Boc protected α- and β-amino acids as well as (-)-cytoxazone.