95614-69-0

Basic information

• Product Name: Cyclohexene, 1-(1-ethenyl-1-propenyl)-, (E)-
• CAS NO: 95614-69-0
• Molecular Formula: C11H16
• Molecular Weight: 148.248
• Mol File: 95614-69-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Cyclohexene, 1-(1-ethenyl-1-propenyl)-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexene, 1-(1-ethenyl-1-propenyl)-, (E)-(95614-69-0)
• EPA Substance Registry System: Cyclohexene, 1-(1-ethenyl-1-propenyl)-, (E)-(95614-69-0)

Safety Data

• Hazardous Substances Data: 95614-69-0(Hazardous Substances Data)

Upstream product

• 65032-23-7 penta-2,3-dien-1-ol 
• 114419-86-2 4-methyl-4-(tetrahydro-2-pyranyloxy)-2-butyn-1-ol 
• 81518-07-2 cyclohex-1-enyl magnesium bromide 
• 89228-82-0 phosphoric acid diethyl ester 2,3-pentadienyl ester 

Relevant articles and documents

SYNTHESE STEREOSELECTIVE DE DIENES CONJUGUES A PARTIR D'ALCOOLS α-ALLENIQUES

The reaction of a Grignard reagent with an α-allenic phosphate leads exclusively in every studied case to 1,3-dienes.A high stereoselectivity is observed for the formation of both double bonds; particularly, the organometallic species attacks preferentially in a trans direction from a group located on the terminal allenic carbon.In the case of the esters of secondary alcohols, it is more difficult to determine the factors which govern the stereochemistry of the other double bond.The Z configuration is then favoured in the reaction phosphate + RMgX but the E configuration is predominant in the reaction acetate + R2CuLi.