956468-49-8

Basic information

• Product Name: trans-dichlorobis[diphenyl(o-phenylphenyl)phosphane]palladium(II)
• Synonyms: trans-dichlorobis[diphenyl(o-phenylphenyl)phosphane]palladium(II)
• CAS NO: 956468-49-8
• Molecular Weight: 854.103
• Mol File: 956468-49-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: trans-dichlorobis[diphenyl(o-phenylphenyl)phosphane]palladium(II)(CAS DataBase Reference)
• NIST Chemistry Reference: trans-dichlorobis[diphenyl(o-phenylphenyl)phosphane]palladium(II)(956468-49-8)
• EPA Substance Registry System: trans-dichlorobis[diphenyl(o-phenylphenyl)phosphane]palladium(II)(956468-49-8)

Safety Data

• Hazardous Substances Data: 956468-49-8(Hazardous Substances Data)

Upstream product

• 12107-56-1 dichloro(1,5-cyclooctadiene)palladium(II) 
• 13885-09-1 [1,1′-biphenyl]-2-yldiphenylphosphane 

Relevant articles and documents

Palladium-catalyzed Suzuki-Miyaura cross-coupling of various aryl halides using ortho-alkyl-substituted arylphosphanes and (ortho-alkylphenyl)- alkylphosphanes under microwave heating

Mono- and dinuclear palladium(II) chloride complexes of various ortho-alkyl-substituted aryl- and alkylphosphanes were prepared. Subsequently, these were characterized by 1H NMR and 31P{1H} NMR spectroscopy, X-ray crystallographic studies and mass spectroscopy. The palladium complexes were screened as potential catalysts for the microwave-assisted Suzuki-Miyaura coupling reaction of several aryl halides under aerobic conditions. A preliminary study showed that excellent results can be obtained even for electron-rich bromides and unactivated aryl chlorides with an optimized solvent, base and catalyst loading using specific phosphane ligands. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.