95666-88-9

Basic information

• Product Name: 2H-Pyran-3-ol, 3,6-dihydro-2-methyl-6-(2-methyl-2-cyclohexen-1-yl)-, acetate
• CAS NO: 95666-88-9
• Molecular Formula: C15H22O3
• Molecular Weight: 250.338
• Mol File: 95666-88-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2H-Pyran-3-ol, 3,6-dihydro-2-methyl-6-(2-methyl-2-cyclohexen-1-yl)-, acetate(CAS DataBase Reference)
• NIST Chemistry Reference: 2H-Pyran-3-ol, 3,6-dihydro-2-methyl-6-(2-methyl-2-cyclohexen-1-yl)-, acetate(95666-88-9)
• EPA Substance Registry System: 2H-Pyran-3-ol, 3,6-dihydro-2-methyl-6-(2-methyl-2-cyclohexen-1-yl)-, acetate(95666-88-9)

Safety Data

• Hazardous Substances Data: 95666-88-9(Hazardous Substances Data)

Upstream product

• 591-49-1 1-methylcyclohex-1-ene 
• 34819-86-8 3,4-di-O-acetyl-6-deoxy-L-glucal 

Relevant articles and documents

C-Glycoside Synthesis via Glycal Alkylation by Olefinic Derivatives

Treatment of peracylated glycals with olefins in the presence of Lewis acids gave 2,3-unsaturated C-glycosides in good to excellent yields.The reaction was completely regioselective and showed a high degree of stereoselectivity leading mostly to the α-isomer.Generally the addition gave the C-glycoside with an unsaturated aglycone.However, with methylenecyclobutane and 1,1 disubstituted linear olefins halogeno derivatives were recovered.The reaction was also performed with acetylated 2-hydroxy glycals.In these conditions keto unsaturated α-C-glycosides were isolated.