95731-73-0Relevant articles and documents
Thiol-Ene Elastomers Derived from Biobased Phenolic Acids with Varying Functionality
Yang, Guozhen,Kristufek, Samantha L.,Link, Lauren A.,Wooley, Karen L.,Robertson, Megan L.
, p. 7737 - 7748 (2016)
The synthesis and physical properties of thiol-ene elastomers derived from plant-based phenolic acids were explored. Phenolic acids of varying functionality (ranging from 2 to 4 hydroxyl and carboxyl groups per molecule) and relative placement of function
Access to Phenolic Fungal Metabolites via the Acid-catalysed Claisen Rearrangement. The Total Synthesis of (+/-)-Mellein, Aurocitrin, and 5',6'-Dihydroaurocitrin
Harwood, Laurence M.
, p. 2577 - 2582 (2007/10/02)
Regioselective trifluoroacetic acid catalysed rearrangement of allyl 5-allyloxy-2-hydroxybenzoate (2b) with concomitant cyclisation of the initial product permits the simple preparation of 3,4-dihydro-5,8-dihydroxy-3-methylisocoumarin (5).Hydrogenolysis of the non-hydrogen bonded hydroxy group yields (+/-)-mellein (7) whereas elaboration of the lactone moiety of compound (5) provides access to aurocitrin (8b) and its side chain analogues.