95778-56-6

Basic information

• Product Name: 1-Cyclohexene-1-methanol, 4-(1-methylenehexyl)-, (S)-
• CAS NO: 95778-56-6
• Molecular Formula: C14H24O
• Molecular Weight: 208.344
• Mol File: 95778-56-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-Cyclohexene-1-methanol, 4-(1-methylenehexyl)-, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Cyclohexene-1-methanol, 4-(1-methylenehexyl)-, (S)-(95778-56-6)
• EPA Substance Registry System: 1-Cyclohexene-1-methanol, 4-(1-methylenehexyl)-, (S)-(95778-56-6)

Safety Data

• Hazardous Substances Data: 95778-56-6(Hazardous Substances Data)

Upstream product

• 109-65-9 1-bromo-butane 
• 536-59-4 (-)-perillyl alcohol 

Relevant articles and documents

The Synthesis of 9-Substituted p-Mentha-1,8(10)-diene Derivatives

The chemical conversion of (+)-limonene (1) and (-)-perillyl alcohol (10) into 9-substituted p-mentha-1,8(10)-diene derivatives is described.The lithiated species of 1 and 10 were easily obtained in good yields, by using sec-butyl lithium in N,N,N',N'-tetramethylethylenediamine.The reaction of the lithiated species (A and B) with various electrophiles was completed within 1-2h to give 9-substituted p-mentha-1,8(10)-diene derivatives.The stereochemistry of the chiral center of the starting material was retained in the products. 9-Hydroxy-p-mentha-1,8(10)-diene(8) was also obtained by another short sequence of steps.Oxidation of the phenylthio derivative (7) gave the sulfoxide (9).Treatment of 9 with trimethyl phosphite afforded 8.Keywords - synthesis; lithiation; limonene; perillyl alcohol; electrophile