958877-81-1

Basic information

• Product Name: (2-tert-butylphenyl)-(2-thiomethyl-benzylidene)-amine
• Synonyms: (2-tert-butylphenyl)-(2-thiomethyl-benzylidene)-amine
• CAS NO: 958877-81-1
• Molecular Weight: 283.437
• Mol File: 958877-81-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2-tert-butylphenyl)-(2-thiomethyl-benzylidene)-amine(CAS DataBase Reference)
• NIST Chemistry Reference: (2-tert-butylphenyl)-(2-thiomethyl-benzylidene)-amine(958877-81-1)
• EPA Substance Registry System: (2-tert-butylphenyl)-(2-thiomethyl-benzylidene)-amine(958877-81-1)

Safety Data

• Hazardous Substances Data: 958877-81-1(Hazardous Substances Data)

Upstream product

• 7022-45-9 2-(methylsulfanyl)benzaldehyde 
• 6310-21-0 2-(1,1-dimethylethyl)-benzenamine 

Downstream Products

• 886-65-7 1,4-diphenyl-1,3-butadiene 
• 92-52-4 biphenyl 

Relevant articles and documents

C-C bond formation via C-H bond activation: Catalytic arylation and alkenylation of alkane segments

A new system for catalytic arylation and alkenylation of alkane segments has been developed. The ortho-tert-butylaniline substrates and 2-pivaloylpyridine may be arylated and alkenylated at the tert-butyl group, while no functionalization occurred at more reactive C-H and other bonds. Arylation and alkenylation of these substrates are achieved in the presence of Ph2Si(OH)Me and Ph-CH=CH-Si(OH)Me2, respectively, and the catalytic amount of Pd(OAc)2 and stoichiometric oxidant (Cu(OAc)2, 2 equiv) in DMF. In contrast, the ortho-i-propylaniline substrate underwent cyclopalladation, but no arylation product was obtained. Complex compound 14 was synthesized via tandem arylation-alkenylation of tert-butylaniline 11. We hypothesize that the high selectivity of this system stems from the confluence of directing effect of the Schiff base or pyridine moiety and unique reactivity properties of a phenyl-palladium acetate species (Ph-Pd-OAc·Ln). Copyright