959032-99-6

Basic information

• Product Name: 3-(4-methoxyphenyl)propyl N,N-diisopropylcarbamate
• Synonyms: 3-(4-methoxyphenyl)propyl N,N-diisopropylcarbamate
• CAS NO: 959032-99-6
• Molecular Weight: 293.406
• Mol File: 959032-99-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3-(4-methoxyphenyl)propyl N,N-diisopropylcarbamate(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(4-methoxyphenyl)propyl N,N-diisopropylcarbamate(959032-99-6)
• EPA Substance Registry System: 3-(4-methoxyphenyl)propyl N,N-diisopropylcarbamate(959032-99-6)

Safety Data

• Hazardous Substances Data: 959032-99-6(Hazardous Substances Data)

Upstream product

• 19009-39-3 N,N-diisopropylcarbamoyl chloride 
• 5406-18-8 3-(p-methoxyphenyl)-1-propanol 

Downstream Products

• 1338073-46-3 (S)-tert-butyldimethyl(9-(4-methoxyphenyl)-7-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)nonyloxy)silane 
• 1338073-38-3 (S)-1-(4-methoxyphenyl)pentan-3-ol 
• 1338073-40-7 (R)-1-(4-methoxyphenyl)-5-methylhexan-3-ol 
• 1338073-45-2 C₁₄H₂₁N₃O₂ 
• 1338073-47-4 (S)-9-(tert-butyldimethylsilyloxy)-1-(4-methoxyphenyl)nonan-3-ol 
• 1338073-63-4 (R)-1-(3-chloropentyl)-4-methoxybenzene 
• 1338073-64-5 (S)-1-(3-chloro-5-methylhexyl)-4-methoxybenzene 
• 1338073-67-8 (S)-7-(1-(4-methoxyphenyl)hex-5-en-3-yl)cyclohepta-1,3,5-triene 
• 1338073-69-0 (R)-1-(7-azido-3-chloroheptyl)-4-methoxybenzene 
• 1338073-70-3 (R)-tert-butyl(7-chloro-9-(4-methoxyphenyl)nonyloxy)dimethylsilane 
• 1338073-39-4 (R)-2-(1-(4-methoxyphenyl)-5-methylhexan-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 1338246-58-4 (R)-4,4,5,5-tetramethyl-2-(3-methyl-1-phenylbutyl)-1,3,2-dioxaborolane 
• 1338073-41-8 (R)-2-(1-(4-methoxyphenyl)hex-5-en-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 1421531-86-3 (E)-1-(hexa-3,5-dien-1-yl)-4-methoxybenzene 

Relevant articles and documents

Synthesis of α-Chiral Ketones and Chiral Alkanes Using Radical Polar Crossover Reactions of Vinyl Boron Ate Complexes

Vinyl boron ate complexes of enantioenriched secondary alkyl pinacolboronic esters undergo stereospecific radical-induced 1,2-migration in radical polar crossover reactions. In this three-component process various commercially available alkyl iodides act as radical precursors and light is used for chain initiation. Subsequent oxidation and protodeborylation leads to valuable α-chiral ketones and chiral alkanes, respectively, with excellent enantiopurity.

Ate complexes of secondary boronic esters as chiral organometallic-type nucleophiles for asymmetric synthesis

The addition of an aryllithium reagent to a secondary boronic ester leads to an intermediate boron-ate complex that behaves as a chiral nucleophile, reacting with a broad range of electrophiles with inversion of stereochemistry. Depending on the electrophile, the C-B bond can be converted into C-I, C-Br, C-Cl, C-N, C-O, and C-C, all with very high levels of stereocontrol. This discovery now adds a new, readily available, configurationally stable, chiral organometallic-type reagent to the arsenal of methods for use in asymmetric organic synthesis.