95953-43-8

Basic information

• Product Name: 5‐(naphthalen‐2‐yl)‐2,3‐diphenyl‐1H‐pyrrole
• Synonyms: 5‐(naphthalen‐2‐yl)‐2,3‐diphenyl‐1H‐pyrrole
• CAS NO: 95953-43-8
• Molecular Weight: 345.444
• Mol File: 95953-43-8.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 5‐(naphthalen‐2‐yl)‐2,3‐diphenyl‐1H‐pyrrole(CAS DataBase Reference)
• NIST Chemistry Reference: 5‐(naphthalen‐2‐yl)‐2,3‐diphenyl‐1H‐pyrrole(95953-43-8)
• EPA Substance Registry System: 5‐(naphthalen‐2‐yl)‐2,3‐diphenyl‐1H‐pyrrole(95953-43-8)

Safety Data

• Hazardous Substances Data: 95953-43-8(Hazardous Substances Data)

Upstream product

• 530-36-9 2-amino-1,2-diphenylethanol 
• 7228-47-9 2-(2-naphthyl)ethanol 
• 177750-24-2 N-(1-(naphthalen-2-yl)vinyl)acetamide 
• 16483-98-0 2,3-diphenyl-2H-azirine 
• 93-08-3 methyl 2-naphthyl ketone 
• 501-65-5 diphenyl acetylene 

Relevant articles and documents

A robust NNP-type ruthenium (II) complex for alcohols dehydrogenation to esters and pyrroles

A Ru (II) complex bearing pyridyl-based benzimidazole-phosphine tridentate NNP ligand was synthesized and structurally characterized by NMR, IR. The complex can efficiently and selectively catalyze the acceptorless dehydrogenation of primary alcohols to esters under relatively mild conditions and the synthesis of pyrroles by means of the reactions of secondary alcohols and β-amino alcohols through acceptorless deoxygenation condensation.

A Versatile Ru(II)-NNP Complex Catalyst for the Synthesis of Multisubstituted Pyrroles and Pyridines

A pincer-type Ru(II)-NNP complex bearing a pyrazolyl-(NH-PtBu2)-pyridine ligand was synthesized and structurally characterized by NMR, IR, elemental analysis, and X-ray single-crystal crystallographic determinations, which efficiently catalyzed the synthesis of multisubstituted pyrroles and pyridines by means of the reactions of secondary alcohols and β- or γ-amino alcohols through deoxygenation and selective C-N and C-C bond formation. The coupling reactions took place with 0.3 mol % catalyst loading and tolerated diverse functional groups. The present work provides an alternative method to construct highly active transition-metal complex catalysts from readily available ligands.

Synthesis of multi-substituted pyrroles using enamides and alkynes catalyzed by Pd(OAc)2 with molecular oxygen as an oxidant

A cyclization reaction between enamides and alkynes catalyzed by palladium(ii) acetate is described. In this method, the molecular oxygen serves as an efficient oxidant for the Pd(ii)/Pd(0) catalytic cycle. The simple reaction conditions permit this methodology to be used as a general tool for the preparation of multi-substituted pyrroles.