959683-25-1

Basic information

• Product Name: C₁₆H₁₈FNO₃
• Synonyms: C₁₆H₁₈FNO₃
• CAS NO: 959683-25-1
• Molecular Weight: 291.322
• Mol File: 959683-25-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: C₁₆H₁₈FNO₃(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₆H₁₈FNO₃(959683-25-1)
• EPA Substance Registry System: C₁₆H₁₈FNO₃(959683-25-1)

Safety Data

• Hazardous Substances Data: 959683-25-1(Hazardous Substances Data)

Upstream product

• 332940-69-9 tert-butyl 4-oxopyridine-1-carboxylate 
• 620-08-6 4-methoxypyridine 
• 24424-99-5 di-tert-butyl dicarbonate 
• 352-13-6 4-flourophenylmagnesium bromide 

Relevant articles and documents

Vinylogous Mukaiyama-Michael Reactions of Dihydropyridinones

An In(III)-catalyzed vinylogous addition of O-silyl vinylketene acetals to 2,3-dihydro-4-pyridinones has been developed. The method features the unprecedented employment of supersilyl groups to influence the γ versus α regiochemical control of vinylogous Mukaiyama-Michael (vM-Michael) reactions when γ-substituted O-silyl vinylketene acetals are used. We also demonstrate that these reactions allow facile access to quinolizidine-based alkaloids such as deoxynupharidine and well as lasubine I and II.