96-08-2

Basic information

• Product Name: 1-METHYL-4-(2-METHYLOXIRANYL)-7-OXABICYCLO[4.1.0]HEPTANE
• Synonyms: 1-METHYL-4-(2-METHYLOXIRANYL)-7-OXABICYCLO[4.1.0]HEPTANE;1-METHYL-4-(1-METHYLEPOXYETHYL)-7-OXABICYCLO[4.1.0]HEPTANE;CAJEPUTENE DIOXIDE;LIMONENE DIOXIDE;CINENE DIOXIDE;Dipentene dioxide;P-MENTHA-1,8-DIENE DIOXIDE;1,2,8,9-Diepoxylimonene
• CAS NO: 96-08-2
• Molecular Formula: C₁₀H₁₆O₂
• Molecular Weight: 168.23
• EINECS: 202-475-1
• Mol File: 96-08-2.mol
• Article Data: 111

Chemical Properties

• Boiling Point: 237.18°C (rough estimate)
• Flash Point: 100.4°C
• Appearance: clear to light yellow liquid
• Density: 0.9607 (rough estimate)
• Vapor Pressure: 0.0431mmHg at 25°C
• Refractive Index: 1.4480 (estimate)
• CAS DataBase Reference: 1-METHYL-4-(2-METHYLOXIRANYL)-7-OXABICYCLO[4.1.0]HEPTANE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-METHYL-4-(2-METHYLOXIRANYL)-7-OXABICYCLO[4.1.0]HEPTANE(96-08-2)
• EPA Substance Registry System: 1-METHYL-4-(2-METHYLOXIRANYL)-7-OXABICYCLO[4.1.0]HEPTANE(96-08-2)

Safety Data

• Hazardous Substances Data: 96-08-2(Hazardous Substances Data)

Usage

General Description

1-METHYL-4-(2-METHYLOXIRANYL)-7-OXABICYCLO[4.1.0]HEPTANE, also known as Anethole, is a chemical compound with the molecular formula C11H16O. It is a bicyclic organic compound that contains a seven-membered ring with one oxygen atom. Anethole is commonly found in essential oils, such as anise and fennel, and is responsible for their distinct aroma and flavor. It is used as a flavoring agent in food and beverages and also has potential medicinal properties, including antimicrobial and antioxidant effects. Anethole has a sweet, aromatic taste and is often used in the production of licorice-flavored products and herbal remedies.

InChI:InChI=1/C10H16O2/c1-9-4-3-7(5-8(9)12-9)10(2)6-11-10/h7-8H,3-6H2,1-2H3

Upstream product

• 5989-54-8 (-)-(S)-limonene 
• 203719-53-3 (-)-limonene oxide 
• 5989-27-5 D-limonene 
• 138-86-3 limonene. 
• 1195-92-2 Limonene oxide 
• 1195-92-2 (4R)-limonene 1,2-epoxide 
• 105-87-3 3,7-dimethyl-2E,6-octadien-1-yl acetate 
• 184488-93-5 (R)-8,9-limonene oxide 
• 28098-67-1 (R)-2-methyl-2-((R)-4-methylcyclohex-3-enyl)oxirane 
• 6909-30-4 (1S,2R,4R)-limonene-1,2-epoxide 
• 28098-68-2 (S)-2-methyl-2-((R)-4-methylcyclohex-3-enyl)oxirane 
• 4680-24-4 cis-(R)-limonene oxide 

Downstream Products

• 1195-92-2 (4R)-limonene 1,2-epoxide 
• 106145-00-0 (6S,1'R)-6-(1'-hydroxy-1',5'-dimethyl-4'-hexenyl)-3-methyl-2-cyclohexenone 
• 95602-94-1 (6S,1'S)-6-(1'-hydroxy-1',5'-dimethyl-4'-hexenyl)-3-methyl-2-cyclohexenone 
• 106144-99-4 (1'R,4'S)-2-(4'-hydroxy-4'-methyl-2'-cyclohexenyl)-6-methyl-5-hepten-2-ol 
• 106144-98-3 (1S,2S,4R)-4-(1'-hydroxy-1',5'-dimethyl-4'-hexenyl)-1-methyl-2-phenylselenocyclohexanol 
• 110654-86-9 (R)-5-(1-Hydroxy-1,5-dimethyl-hex-4-enyl)-2-methyl-2-phenylselanyl-cyclohexanol 
• 110654-87-0 (1'S,3'R)-2-(3'-hydroxy-4'-methylcyclohexenyl)-6-methyl-5-hepten-2-ol 
• 110715-84-9 (-)-hernandulcin 
• 110715-85-0 (6R,1'S)-epi-hernandulcin 
• 106144-99-4 (1'S,4'R)-2-(4'-hydroxy-4'-methyl-2'-cyclohexenyl)-6-methyl-5-hepten-2-ol 
• 106144-98-3 (1R,2R,4S)-4-(1'-hydroxy-1',5'-dimethyl-4'-hexenyl)-1-methyl-2-phenylselenocyclohexanol 
• 110654-86-9 (S)-5-(1-Hydroxy-1,5-dimethyl-hex-4-enyl)-2-methyl-2-phenylselanyl-cyclohexanol 
• 106144-99-4 (R)-4-(1-Hydroxy-1,5-dimethyl-hex-4-enyl)-1-methyl-cyclohex-2-enol 
• 106144-98-3 (R)-4-(1-Hydroxy-1,5-dimethyl-hex-4-enyl)-1-methyl-2-phenylselanyl-cyclohexanol 

Relevant articles and documents

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Liquid-phase oxidation of olefins with rare hydronium ion salt of dinuclear dioxido-vanadium(V) complexes and comparative catalytic studies with analogous copper complexes

Homogeneous liquid-phase oxidation of a number of aromatic and aliphatic olefins was examined using dinuclear anionic vanadium dioxido complexes [(VO2)2(salLH)]? (1) and [(VO2)2(NsalLH)]? (2) and dinuclear copper complexes [(CuCl)2(salLH)]? (3) and [(CuCl)2(NsalLH)]? (4) (reaction of carbohydrazide with salicylaldehyde and 4-diethylamino salicylaldehyde afforded Schiff-base ligands [salLH4] and [NsalLH4], respectively). Anionic vanadium and copper complexes 1, 2, 3, and 4 were isolated in the form of their hydronium ion salt, which is rare. The molecular structure of the hydronium ion salt of anionic dinuclear vanadium dioxido complex [(VO2)2(salLH)]? (1) was established through single-crystal X-ray analysis. The chemical and structural properties were studied using Fourier transform infrared (FT-IR), ultraviolet–visible (UV–Vis), 1H and 13C nuclear magnetic resonance (NMR), electrospray ionization mass spectrometry (ESI-MS), electron paramagnetic resonance (EPR) spectroscopy, and thermogravimetric analysis (TGA). In the presence of hydrogen peroxide, both dinuclear vanadium dioxido complexes were applied for the oxidation of a series of aromatic and aliphatic alkenes. High catalytic activity and efficiency were achieved using catalysts 1 and 2 in the oxidation of olefins. Alkenes with electron-donating groups make the oxidation processes easy. Thus, in general, aromatic olefins show better substrate conversion in comparison to the aliphatic olefins. Under optimized reaction conditions, both copper catalysts 3 and 4 fail to compete with the activity shown by their vanadium counterparts. Irrespective of olefins, metal (vanadium or copper) complexes of the ligand [salLH4] (I) show better substrate conversion(%) compared with the metal complexes of the ligand [NsalLH4] (II).

A new and efficient methodology for olefin epoxidation catalyzed by supported cobalt nanoparticles

A new heterogeneous catalytic system consisting of cobalt nanoparticles (CoNPs) supported on MgO and tert-butyl hydroperoxide (TBHP) as oxidant is presented. This CoNPs@MgO/t-BuOOH catalytic combination allowed the epoxidation of a variety of olefins with good to excellent yield and high selectivity. The catalyst preparation is simple and straightforward from commercially available starting materials and it could be recovered and reused maintaining its unaltered high activity.