960207-08-3Relevant articles and documents
Stereoselective synthesis of (R)-(+)-1-methoxyspirobrassinin, (2R,3R)-(-)-1-methoxyspirobrassinol methyl ether and their enantiomers or diastereoisomers
?urillová, Zuzana,Kutschy, Peter,Budovská, Mariana,Nakahashi, Atsufumi,Monde, Kenji
, p. 8200 - 8204 (2007)
Stereoselective synthesis of cruciferous indole phytoalexin (R)-(+)-1-methoxyspirobrassinin and its unnatural (S)-(-)-enantiomer was achieved by spirocyclization of 1-methoxybrassinin in the presence of (+)- and (-)-menthol and subsequent oxidation of the