960408-51-9

Basic information

• Product Name: butyl 3-(1-phenylvinylthio)propanoate
• Synonyms: butyl 3-(1-phenylvinylthio)propanoate
• CAS NO: 960408-51-9
• Molecular Weight: 264.389
• Mol File: 960408-51-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: butyl 3-(1-phenylvinylthio)propanoate(CAS DataBase Reference)
• NIST Chemistry Reference: butyl 3-(1-phenylvinylthio)propanoate(960408-51-9)
• EPA Substance Registry System: butyl 3-(1-phenylvinylthio)propanoate(960408-51-9)

Safety Data

• Hazardous Substances Data: 960408-51-9(Hazardous Substances Data)

Upstream product

• 16215-21-7 butyl 3-mercaptopropionate 
• 536-74-3 phenylacetylene 

Relevant articles and documents

Synthesis of 1,1-disubstituted alkyl vinyl sulfides via rhodium-catalyzed alkyne hydrothiolation: Scope and limitations

(Chemical Equation Presented) Described herein are the scope and limitations using Tp*Rh(PPh3)2 as a catalyst for alkyne hydrothiolation with alkyl thiols. In general, catalytic hydrothiolation proceeds in high yields and with high regioselectivity for a wide range of alkynes and thiols. A variety of functional groups were well-tolerated, including nitriles, amines, halogens, ethers, esters and silanes, although strongly coordinating groups were found to be incompatible with hydrothiolation. Both sterically encumbered alkynes and thiols were successful in hydrothiolation. Electron rich alkynes react more rapidly than electron deficient alkynes. Overall, this hydrothiolation protocol provides convenient access to a variety of functionalized branched alkyl vinyl sulfides.