96203-90-6Relevant articles and documents
Hydroquinone derivatives useful in the production of vitamin E
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, (2008/06/13)
The present invention is directed to novel hydroquinone derivatives which are useful as intermediates for the manufacture of (R,R,R)-α-tocopherol (natural vitamin E) as well as of racemic α-tocopherol. The invention is also directed to a process for the preparation of the hydroquinone derivatives of the invention.
AN EFFICIENT SYNTHESIS OF (S)-CHROMANMETHANOL, A VITAMIN E PRECURSOR
Takabe, Kunihiko,Okisaka, Koichi,Uchiyama, Yujiro,Katagiri, Takao,Yoda, Hidemi
, p. 561 - 562 (2007/10/02)
The (S)-chromanmethanol, a key intermediate for the synthesis of optically active α-tocopherol was synthesized by a reaction sequence which utilized the asymmetric epoxidation of the (E)-allylic alcohol to the (2R,3R)-epoxyalcohol in high enantiomeric exc