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96277-63-3

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96277-63-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 96277-63-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,6,2,7 and 7 respectively; the second part has 2 digits, 6 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 96277-63:
(7*9)+(6*6)+(5*2)+(4*7)+(3*7)+(2*6)+(1*3)=173
173 % 10 = 3
So 96277-63-3 is a valid CAS Registry Number.

96277-63-3Relevant articles and documents

Kinetic studies on the reactions of electrogenerated 9,10-diphenyl-anthracene cation radical with water and alcohols by means of column-electrolytic stopped-flow method

Oyama,Nozaki,Nagaoka,Okazaki

, p. 33 - 41 (2007/10/02)

The reactions of 9,10-diphenylanthracene cation radical (DPA+.) with water and alcohols in acetonitrile (AN) were studied using a novel column-electrolytic stopped-flow spectrophotometric method. The reaction was first-order with respect to DPA+. in all reactions. The reaction orders of other reactants were determined by plotting the logarithms of the apparent first-order rate constants (k(app)'s) against the logarithms of the concentration of reactants. The plot of log k(app) vs. log [alcohols] was linear, and hence the reaction was clearly determined to be second-order. On the other hand, the log k(app) vs. log [water] plot did not show a linear relationship. Similar results were obtained in the reactions of 9,10-dimethylanthracene cation radical with water and methanol. Comparing the results obtained with water and alcohols, and considering the changes in the physicochemical properties of the AN-water medium, it was concluded that the reaction of water was second-order, though it had been believed previously to be first-order. Products of the reactions are trans- and cis-9,10-dialkoxy-9,10-diphenyl-9,10-dihydroanthracene in many cases.

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